Experiment and pu tiron nail into water

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Discussion Overview

The discussion revolves around an experiment involving the rusting of a steel nail submerged in water, exploring the chemical processes involved in rust formation and the effects of electrolysis on the nail. Participants examine the transition from green rust to red rust and the implications of weight changes during rusting and de-rusting processes.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant describes the rusting process of iron, outlining the chemical reactions that lead to the formation of green rust and subsequently red rust, questioning the conditions under which red rust forms.
  • Another participant provides references to the crystal structure of green rust and discusses how the presence of oxygen and iron(III) content can affect the color of the precipitate.
  • Several participants note that the nail is likely made of steel, which may contain impurities that influence the rusting process and weight changes during electrolysis.
  • Questions arise about the weight gain of the nail during rusting and whether it would lose weight during de-rusting, with some participants suggesting that oxidation could lead to mass gain from the formation of oxides or hydroxides.
  • Participants inquire about the specific reactions occurring at the cathode during electrolysis, including the formation of FeCl2 and the potential liberation of hydrogen gas.
  • One participant mentions the formation of green substances around the sacrificial iron anode, expressing uncertainty about their identity.
  • There is a discussion about the accuracy of mass measurements during the experiment, with one participant noting that the presence of green material may affect the recorded weight of the nail.

Areas of Agreement / Disagreement

Participants express various viewpoints regarding the chemical processes involved in rust formation and the implications of weight changes during electrolysis. No consensus is reached on the specific conditions affecting the transition from green rust to red rust or the reasons behind the weight changes observed.

Contextual Notes

Participants mention potential impurities in the water and the composition of the nail, which may influence the results. The discussion includes unresolved questions about the specific reactions taking place during electrolysis and the measurement conditions for the nail's weight.

Who May Find This Useful

This discussion may be of interest to individuals studying corrosion processes, electrochemistry, or those conducting similar experiments involving rust and electrolysis.

Mathysics
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So i did an experiment and pu tiron nail into water and serveral days later it starts to rust.

and i looked at the book and the chemical process is
1)Fe loses electron
2) that electron + oxygen + water produces hydroxide
3) hydroxide and Fe ion reacts and form Fe(OH)2, green rust
4) green rust + oxygen become red rust + water

but i don't know why it is red rust that is formed on the nail. If the pH level is low will it becomes red rust or stays at green rust?

THX!
 
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Crystal structure of green rust formed by corrosion of cast iron
http://www.nature.com/nature/journal/v259/n5540/abs/259200a0.html

http://en.wikipedia.org/wiki/Iron(II)_hydroxide
If the solution was not deoxygenated and the iron reduced, the precipitate can vary in color starting from green to reddish brown depending on the iron(III) content.
Look at the possible reactions of Fe and aqueous solutions, and also at the forms of Fe oxides, hydroxides and oxyhydroxides.

Are there any cation impurities or alloying elements?
 


well the h2o will have impurities, and the nail is actually steel and iron?

As part of the experiment i am also to de rust the nail.

would the nail suppose the gain weigh after electrolysis? Because when the nail rust it gains weigh, and if de rust will it lose weigh? but my nail gains weigh after electrolysis and I have no idea why is that...
 


Mathysics said:
well the h2o will have impurities, and the nail is actually steel and iron?

As part of the experiment i am also to de rust the nail.

would the nail suppose the gain weigh after electrolysis? Because when the nail rust it gains weigh, and if de rust will it lose weigh? but my nail gains weigh after electrolysis and I have no idea why is that...
The nail is probably steel, i.e. an alloy of iron. It would gain mass from the oxidation of the steel components, i.e., pickup oxygen in the form of oxides, or hydroxides.
 


Astronuc said:
The nail is probably steel, i.e. an alloy of iron. It would gain mass from the oxidation of the steel components, i.e., pickup oxygen in the form of oxides, or hydroxides.
well yes when the nail form rust it is heavier but I am not sure about the cathode (rusted iron) will gain or lose weight. I re-tested again at school day and still got the same result. So my question is how come the nail rust it gains weight, and when the nail being de-rusted it gains weight again?

Oh.. also the anode iron (sacrifical iron) forms green stuff aorund it, I am not sure what that is too!
 
Last edited:


How much mass is gained?

In addition to forming oxides with iron and other steel components, there may be spinels or other complex oxides. Is the electrolyte solution aerated or de-aerated water?

Note: reduction occurs at the cathode. So mass deposition would occur at that cathode.

http://bouman.chem.georgetown.edu/S02/lect25/lect25.htm
bouman.chem.georgetown.edu/S02/lect25/e3a.jpg

Also note the different reactions with water. Even in electrolysis, if one liberates hydrogen, the oxygen is available to react with the cathode.

What reactions are taking place in the cell, particularly at the cathode?
 


Astronuc said:
How much mass is gained?

In addition to forming oxides with iron and other steel components, there may be spinels or other complex oxides. Is the electrolyte solution aerated or de-aerated water?

Note: reduction occurs at the cathode. So mass deposition would occur at that cathode.

http://bouman.chem.georgetown.edu/S02/lect25/lect25.htm
bouman.chem.georgetown.edu/S02/lect25/e3a.jpg

Also note the different reactions with water. Even in electrolysis, if one liberates hydrogen, the oxygen is available to react with the cathode.

What reactions are taking place in the cell, particularly at the cathode?

the cathode nail takes 25mins to gain 2.36 -> 2.4. This is not too accurate because there are those (green stuff?) form around the nail and when i pull the nail out and measure the weight those green stuff fall out and stay in solution.

solution is HCl

the rust on cathode nail should be forming FeCl2 then will form iron as the cathode nail becomes negative? Is hydrogen gas also produced at cathode?
 


By 2.36 -> 2.4, is this a mass changing from 2.36 g to 2.4 g? I presume units are grams.

Does one measure the nail both times in the same condition, i.e. dry?
 


Astronuc said:
By 2.36 -> 2.4, is this a mass changing from 2.36 g to 2.4 g? I presume units are grams.

Does one measure the nail both times in the same condition, i.e. dry?

sorry my computer was having some problems...

yes it changes from 2.36 to 2.6 in grams and are both measured in the same condition
 

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