Finding meaning in the Phase of the wavefunction

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The discussion centers on calculating the expectation value of a new wavefunction defined as ##\psi_{new}(x) = e^{-iqx/\hbar} \psi_{0}##, where ##\psi_{0}## is a normalized wavefunction. The expectation value is determined to be ##q + p_{0}##, with the integral of ##\psi_{0}^{2}## equating to 1 due to normalization. Participants clarify that while certain eigenfunctions can be real, not all wavefunctions are necessarily real-valued. The conversation also emphasizes that eigenvalues of Hermitian operators, which correspond to physical observables, are always real, while eigenvalues of other operators can be complex. The discussion concludes with a consensus on the importance of careful language regarding wavefunctions and eigenvalues in quantum mechanics.
Irishdoug
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Homework Statement
Suppose ##\psi_{0}## is a properly normalised wavefunction with ##<x_{\psi_0} >## = ##x_{0}## and ##<p_{\psi_0} >## = ##p_{0}##. Define a new wavefunction ##\psi_{new}##(x) = ##e^{{-iqx}/{\hbar}}## ##\psi_{0}##
Relevant Equations
N/A
Suppose ##\psi_{0}## is a properly normalised wavefunction with ##<x_{\psi_0} >## = ##x_{0}## and ##<p_{\psi_0} >## = ##p_{0}##. Define a new wavefunction ##\psi_{new}##(x) = ##e^{{-iqx}/{\hbar}}## ##\psi_{0}##

What is the expectation value ##<\psi_{new}>## in the state given by ##\psi_{new}##(x)?

The answer to the question is given here: https://ocw.mit.edu/courses/physics...pring-2013/assignments/MIT8_04S13_ps6_sol.pdf (It is ##q + p_{0}##)

In doing the question myself I got as far as (##-i \hbar##) ##(\frac{iq}{\hbar})## ##\int_{-\infty}^{+\infty} \psi_{0} e^{-iqx/\hbar} \psi_{0} e^{iqx/\hbar} dx ## + (##-i \hbar##) ##\int_{-\infty}^{+\infty} \psi_{0} e^{-iqx/\hbar} \psi_{0}' e^{iqx/\hbar} dx ##

Now, the 2nd integral on the right is just equal to ##p_{0}## . It is not clear to me how the first integral reduces to just q to give the answer of ##q + p_{0}## as we are left with ##\int_{-\infty}^{+\infty} \psi_{0}^{2} e^{0} dx ##

I did the integral and it is divergent. Does this mean it is treated as being 1 as it's unphysical and we are just left with q after the cancelations of i and ##\hbar##?
 
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Ok I just realized after writng that all out that
##\int_{-\infty}^{+\infty} \psi_{0}^{2} dx ## is the probability density function which is = 1 by definition so I'm guessing that is why it reduces to 1?
 
Irishdoug said:
Ok I just realized after writng that all out that
##\int_{-\infty}^{+\infty} \psi_{0}^{2} dx ## is the probability density function which is = 1 by definition so I'm guessing that is why it reduces to 1?

You should have ##\psi_0^* \psi_0## in those integrals.
 
Is it not the case that ##\psi_{0}## can be taken to be real as such ##\psi^{*}_{0}## = ##\psi_{0}##?
 
Irishdoug said:
Is it not the case that ##\psi_{0}## can be taken to be real as such ##\psi^{*}_{0}## = ##\psi_{0}##?
Not in general.
 
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Ok, I thought this was a general rule as such.
 
Irishdoug said:
Ok, I thought this was a general rule as such.
You can often choose a set of particular eigenfunctions to be real-valued. But, that's different from any set of eigenfunctions being real-valued.
 
Am I correct in saying that the eigenvalue has to be real-valued though?
 
Irishdoug said:
Am I correct in saying that the eigenvalue has to be real-valued though?
Eigenvalues of a Hermitian operator are real.
 
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Ok, I need to be more careful with my language then. I thought in QM, in general, eigenvalues had to be real. I am assuming this presumption is incorrect?
 
  • #11
Irishdoug said:
Ok, I need to be more careful with my language then. I thought in QM, in general, eigenvalues had to be real. I am assuming this presumption is incorrect?

The eigenvalues of operators in general are complex numbers. E.g. the eigenvalues of the lowering (annihilation) operator for the SHO can be any complex number.

The eigenvalues of Hermitian operators, which represent observables, are real.

In this case, however, all the problem says is that ##\psi_0## is a normalised wavefunction. You can't assume anything further.
 
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  • #12
PeroK said:
The eigenvalues of operators in general are complex numbers. E.g. the eigenvalues of the lowering (annihilation) operator for the SHO can be any complex number.

The eigenvalues of Hermitian operators, which represent observables, are real.

In this case, however, all the problem says is that ##\psi_0## is a normalised wavefunction. You can't assume anything further.

Ah that makes perfect sense now. Thankyou!
 

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