Frictional force opposes relative motion, not just motion itself, as illustrated by a conveyor belt scenario where static friction allows objects to accelerate with the moving belt. When the belt starts moving, static friction acts between the belt and the objects, enabling them to move together. In contrast, kinetic friction occurs when there is slipping, such as between a car's tires and the road, which prevents acceleration. The force of static friction between the tires and the road is crucial for the car's acceleration, as slipping would hinder this process. Overall, friction plays a vital role in facilitating motion by opposing relative motion between surfaces in contact.