Ground state energy in Optical Spectroscopy & Atomic Structure

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SUMMARY

The discussion centers on the calculation of ground state energy in atomic structures, specifically comparing Hydrogen and Helium. The ground state energy of Hydrogen is established at 13.6 eV. For neutral Helium, exact solutions for ground state energy are unattainable, necessitating numerical approximations. However, for singly-ionized Helium (He+), an exact solution can be derived, highlighting the need for clarity in problem statements regarding the atomic state in question.

PREREQUISITES
  • Understanding of atomic structure and energy levels
  • Familiarity with quantum mechanics principles
  • Knowledge of numerical approximation methods
  • Experience with solving Schrödinger's equation for hydrogen-like atoms
NEXT STEPS
  • Research the numerical methods for approximating ground state energies in multi-electron atoms
  • Study the exact solutions for hydrogen-like ions, focusing on He+
  • Explore the implications of quantum mechanics on atomic structure
  • Investigate the differences between neutral and ionized atomic states
USEFUL FOR

Students and researchers in atomic physics, quantum mechanics enthusiasts, and anyone involved in theoretical chemistry or spectroscopy who seeks to understand atomic energy states.

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Homework Statement



I just want to know if there is a relationship between the ground state of Hydrogen which is 13.6 eV and the ground state of Helium. The problem is asking me to find the ground state of Helium, but I am not sure how to go about it. Any advice?

Homework Equations





The Attempt at a Solution

 
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It is not possible to find an exact solution for the ground (or any other) state in neutral helium atoms. Only numerical approximations are possible.

However, if the problem is actually asking to find the ground state in singly-ionized helium, He+, an exact solution is possible. Can you clarify what the problem is really asking for?
 

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