Heat capacity using Debye dispersion relation

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SUMMARY

The discussion focuses on calculating the heat capacity of a harmonic, monatomic, one-dimensional lattice using the Debye dispersion relation. The heat capacity is derived from the equation C_{lattice}=k_{B}\sum_p \int^{\infty}_{0} \frac{Lk_{B}T}{hv\pi}\frac{x^{2}e^{x}}{(e^{x}-1)^{2}} D_{p}(\omega) d\omega, where the spring constants for longitudinal and transverse modes are defined as CL = C and CT = 0.2C, respectively. The final expression for heat capacity is C_{lattice} = \frac{\pi L k_{B}}{3h}\sqrt{\frac{M}{c_{p}}}KT(2\sqrt{5}+1). Corrections to the initial expression were noted, particularly regarding the denominator in the integral.

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Homework Statement


Using the Debye dispersion approximation, calculate the heat capacity of a harmonic, monatomic, 1D lattice. Next, find the temperature dependence in the low temperature limit. (Assume that the longitudinal mode has spring constant CL = C, and the two transverse modes both have spring constant CT = 0.2C. )

Homework Equations


C_{lattice}=k_{B}\sump ∫d\omegaDp(\omega) \frac{x^{2}e^{x}}{(e^{x}-1)^{2}} , p is over all of the modes
d\omega D_{p}( \omega) = \frac{Lk_{B}T}{hv\pi}dx
where D_{p}( \omega) = density of states
c_p = the spring constants for longitudinal and transverse

The Attempt at a Solution


So I should end up with 3 heat capacities to add together, two transverse and one longitudinal.

C_{lattice}=k_{B}\sum_p \int^{\inf}_{0} \frac{Lk_{B}T}{hv\pi}\frac{x^{2}e^{x}}{(e^{x}-1)^{2}}<br /> \omega D_{p}(\omega) = \sum_{p}\frac{Lk_{B}T}{hv\pi}\frac{\pi^{2}}{3}K\sqrt{\frac{M}{c_{p}}}

C_{lattice} = \frac{\pi L k_{B}}{3h}\sqrt{\frac{M}{c_{p}}}KT(2\sqrt{5}+1)
So this right here is my final solution, and I'm trying to see how far off base I am.
 
Last edited:
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That was a mistake and should've been (e^{x}-1), and the expression for C_{lattice} is from Kittel if youre wondering where I got it.
 

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