Heat conductivity depending on temperature

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SUMMARY

The discussion focuses on calculating the thermal conductivity of nitrogen gas (N2) as a function of temperature using a Visual Basic function. The provided equation is an empirical fit derived from experimental data, specifically designed for gaseous N2. The constants in the equation are selected to optimize the curve fit to measured values, but their physical significance is limited without context on temperature and pressure ranges. For a more comprehensive understanding, the NIST REFPROP documentation is recommended as it offers a detailed theoretical framework and experimental references.

PREREQUISITES
  • Understanding of thermal conductivity and its significance in heat transfer.
  • Familiarity with empirical equations and their applications in engineering.
  • Basic knowledge of Visual Basic programming for interpreting the provided function.
  • Awareness of temperature and pressure dependencies in gas properties.
NEXT STEPS
  • Review the NIST REFPROP documentation for detailed equations and empirical data on thermal conductivity.
  • Explore the derivation and application of empirical fits in thermodynamics.
  • Investigate the impact of temperature and pressure on the thermal properties of gases.
  • Learn about alternative methods for calculating thermal conductivity, such as using polynomial regression techniques.
USEFUL FOR

Mechanical engineering students, thermal engineers, and researchers involved in heat exchanger design and analysis, particularly those focusing on gas thermal properties.

Oli Hall
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Hi, I'm working on my final year project for a part time mechanical engineering design degree course. I've built and tested a heat exchanger which is used for controlling the temperature of N2 gas.

I'm currently working through the calculations so I can compare real against calculated values.

I'm struggling to calculate the thermal conductivity of N2 depending on temperature. An Engineer from work gave me a Visual basic file which had the following expression which works really well. The problem is I can't work out what the components are - and I'm not happy using it if I don't understand what it's doing


Visual basic expression.

Function lambda_N2 (Temp As Double)

' Calculation of heat conductivity (W/(m*K)) depending on temperature
' for gaseous N2 - source Malkov

lambda_N2 = 0
lambda_N2 = -0.000000054111 * Temp * Temp + 0.000102445 * Temp - 0.00016339

End Function

I assume that the values he's used are constants - but as yet I've been unable to trace them. Could someone explain what some or all of it is doing?

Or is there another way of calculating thermal conductivity?
(Note. I want it for an individual temperature not for ∆T)

Many thanks in advance
Oli
 
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Hi Oli, welcome to PF.

The equation looks like an empirical fit to experimentally measured results (and as such, has little meaning without a temperature and pressure range). The constants are likely selected just to make the resulting curve fit well to measured values.

A much more involved equation with physical justification is given http://www.boulder.nist.gov/div838/theory/refprop/NAO.PDF" , which may be what you're looking for. The document also includes many references to experimental work, which may be useful.
 
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