Help with understanding the uncertainty principle

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Homework Help Overview

The discussion revolves around understanding the uncertainty principle in quantum mechanics, specifically in relation to calculating the mean kinetic energy of an electron based on its momentum uncertainty. The original poster is working on an assignment that involves determining the lowest possible mean kinetic energy given a specific confinement radius for the electron.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the application of the uncertainty principle and its implications for kinetic energy calculations. There are attempts to derive expressions for kinetic energy based on momentum uncertainty and questions about the validity of certain equations related to kinetic energy and total energy in stationary states.

Discussion Status

Participants are actively engaging with the problem, questioning assumptions about kinetic energy in stationary states, and exploring different interpretations of the uncertainty principle. Some guidance has been offered regarding the relationship between momentum uncertainty and kinetic energy, though no consensus has been reached on the validity of specific expressions.

Contextual Notes

There is mention of a fellow student's input, which raises questions about the correctness of assumptions regarding kinetic energy in a stationary system. The discussion also reflects uncertainty about how to properly apply derived expressions in the context of the problem.

sodper
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[SOLVED] Help with understanding the uncertainty principle

I may have posted this in the wrong forum. If so I am sure a moderator could move it to the correct one.

Problem statement:
I have an assignment in which I need to calculate the lowest possible mean of an electron's KE , <KE>, based on the uncertainty of the electron's moment.

Given data:
The radius in which the electron is allowed to move, d=2.81*10^-10

Attempt at solution:
The uncertainty of the electrons position corresponds to d, deltax=d

Using the uncertainty principle I got, deltap = hbar/(2*deltax), where deltap is the lowest possible deviation.

I got deltaKE from, deltaKE = deltap^2/(2m), (m is the electron mass)

A fellow student explained to me that because my problem involves a stationary system (an electron bound to an atom), <KE> should be zero, which gives me:

(deltaKE)^2 = <KE^2> - <KE>^2 => (deltaKE)^2 = <KE^2>

But how do I proceed from here?
 
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sodper said:
I may have posted this in the wrong forum. If so I am sure a moderator could move it to the correct one.

Problem statement:
I have an assignment in which I need to calculate the lowest possible mean of an electron's KE , <KE>, based on the uncertainty of the electron's moment.

Given data:
The radius in which the electron is allowed to move, d=2.81*10^-10

Attempt at solution:
The uncertainty of the electrons position corresponds to d, deltax=d

Using the uncertainty principle I got, deltap = hbar/(2*deltax), where deltap is the lowest possible deviation.

I got deltaKE from, deltaKE = deltap^2/(2m), (m is the electron mass)

A fellow student explained to me that because my problem involves a stationary system (an electron bound to an atom), <KE> should be zero,
Ah... the good ol' "fellow student". Unfortunately, the fellow student is often not correct. For a stationary state [itex]\delta <H>[/itex] is zero, not <KE> (where H=KE + PE). The way you were proceeding previously by considering delta p as related to the given delta x looks fine to me.
 
for example, if the electron is confined to an atom of size 'a' then the KE is roughly
[tex] \frac{\hbar^2}{m a^2}[/tex]
(c.f. particle in a box energy levels (\frac{\hbar^2 \pi^2}{2 m a^2}), etc).
 
I don't think I quite understand. Did you, as I did, derive the expression for the KE from KE = p^2/(2m) ?
I simply substituted p with deltap to get the min deviation in KE.

I'm not sure how I am supposed use the expression of H.
 
sodper said:
I don't think I quite understand. Did you, as I did, derive the expression for the KE from KE = p^2/(2m) ?
I simply substituted p with deltap to get the min deviation in KE.
yeah. that's right.

I'm not sure how I am supposed use the expression of H.
dont use it for anything; I was just pointing out that in a stationary state it is the *total* energy which has no variance, not the *kinetic* energy.
 
Ok, but is the expression (deltaKE)^2 = <KE^2> valid?

If so, can I just take the square root to get the mean KE?
 
sodper said:
Ok, but is the expression (deltaKE)^2 = <KE^2> valid?

no... but we are just getting rough estimates here. That's all that is required. That's why we are using the "equation"

KE "=" (delta p)^2/2m

where (delta p) is given by \hbar divided by (delta x).
 
I see. Thanks! You've made it a lot clearer.

I'll post again if I need more help.
 

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