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NucEngMajor
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How can position^2 expectation be greater than the Length of "box"? I mean <x^2> = L^2 / 3. Say L=100m then we have <x^2> = 333m. How is this possible?
The expectation of position squared being greater than the length of a position is a result of the uncertainty principle in quantum mechanics. This principle states that it is impossible to know the exact position and momentum of a particle at the same time.
One example is the case of a free particle in a one-dimensional box. In this scenario, the expectation value of position squared is equal to the length of the box squared, which is greater than the length of the box itself.
The uncertainty principle states that the more precisely we know the position of a particle, the less precisely we know its momentum, and vice versa. This means that the expectation value of position squared can be larger than the length of a position due to the inherent uncertainty in the measurement of position and momentum.
The uncertainty principle applies to all particles, including atoms, molecules, and subatomic particles. It is a fundamental principle in quantum mechanics and plays a crucial role in understanding the behavior of matter at a microscopic level.
The concept of wave-particle duality states that particles can exhibit both wave-like and particle-like behaviors. This means that the exact position of a particle cannot be known with certainty, as it is described by a wave function that can spread out over a range of positions. Therefore, the expectation value of position squared can be larger than the length of a position due to the probabilistic nature of the particle's position.