How Do You Calculate Equilibrium Partial Pressures in a Chemical Reaction?

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Discussion Overview

The discussion revolves around calculating equilibrium partial pressures for the chemical reaction 2 HI(g) <--> H2(g) + I2(g) at a temperature of 600 K, given an initial pressure of HI and the equilibrium constant.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant presents the initial conditions and attempts to set up the equilibrium expression using the equilibrium constant.
  • Another participant points out an inconsistency in the quadratic solution derived from the equilibrium expression.
  • A third participant confirms the quadratic approach but expresses uncertainty about the next steps to find the partial pressures.
  • A later reply indicates that one participant identified and corrected their earlier error in the calculations.

Areas of Agreement / Disagreement

There is no consensus on the correctness of the calculations, as participants express uncertainty and identify potential errors in the mathematical approach.

Contextual Notes

Participants have not fully resolved the mathematical steps involved in solving the equilibrium expression, and there are indications of missing assumptions in the calculations.

Xels
Messages
19
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0

Homework Statement



At 600 K the equilibrium constant is 38.6 for the reaction

2 HI(g) <--> H2(g) + I2(g)

Start with a pressure of 0.725 atm consisting of only HI(g) at 600 K. Calculate the equilibrium
partial pressures of HI, H2 and I2.

Homework Equations


K=[C]^n[D]^n/[A]^n
Qp = 0 (shift to the right)
ax^2+bx+c
x=((-b+/-((b^2-4ac)^(1/2)))/(2a))


The Attempt at a Solution


Given the gas state atm is treated as mol

2HI H2 I2
I .725 0 0
C -2x x x
E .725-x x x

38.6 = (x*x)/(.725-x)^2
38.6 = (x*x)/(x^2-1.45x+.526)
x^2-1.45x-38.074 = 0

x=((1.45+/-((1.45^2-4*1*38.074)^(1/2)))/(2*1))
+x= 5.48
-x = -6.94 (discounted)

I'm either doing it totally wrong or I'm clueless as to where to go from here. I'm assuming I need to find the final pressure of x and then calculate partial pressure using Pa/Pt etc.
 
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Xels said:
C -2x x x
E .725-x x x

Some inconsistency here...

And I have not checked details, but solving

38.6 = (x*x)/(.725-x)^2

doesn't yield

+x= 5.48
-x = -6.94
 
I got +/- x by solving (x*x)/(.725-x)^2 quadratically. I'm not sure where to go past this to find partial pressures.
 
After much reworking I found my error. Thanks for your input Borek.
 

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