How Do You Calculate the Density of LiCl in a Face-Centered Cubic Structure?

Click For Summary
To calculate the density of LiCl in a face-centered cubic (FCC) structure, the distance between Li+ and Cl- ions is 0.257 nm, and the molecular mass is 42.4 g/mol. The density formula used is ρ = m/V, where the volume (V) is derived from the unit cell dimensions. The correct approach involves recognizing that there are effectively two formula units of LiCl per unit cell in an FCC structure, leading to the factor of 2 in the volume calculation. Clarification is needed on why the factor of 1/2 is used, as it relates to the contribution of ions in the crystal lattice. Understanding the FCC arrangement is crucial for accurate density calculations.
roeb
Messages
98
Reaction score
1

Homework Statement


The distance between the Li+ and Cl- ions in a LiCl is .257 nm. Use this and the molecular mass of LiCl 42.4 g/mol to compute the density of LiCl.

Homework Equations


The Attempt at a Solution


I am surprisingly having a lot of difficultly with this problem.
The LiCl crystal is face centered (as far as I can tell) so there is an entire LiCl and either a Li or Cl in the center (I think Cl, but I'm not sure).

If I follow the example in the book I can simply find the answer, but it doesn't make sense.

\rho = m/V = 42.4 / (2 * 6.02 x 10^23 * r0^3)

This works but I don't understand it. Here is how I attempted to do it...

\rho = m/V = (42.4 + 1/2 42.4) / (6.02 x 10^23 * r0^3)

I am assuming that since the problem doesn't give the information I can't look up whether or not Cl is in the middle or even the mass of Li and Cl separately. So I took 1/2 the mass of LiCl hoping that would average out. Unfortunately that gives an incorrect answer.

Does anyone have a way to explain why 1/2 is the correct factor in this case? It seems strange to me.
 
Physics news on Phys.org
sorry, i seem to have confused fcc with bcc...
 
The book claims the answer is that all the magnitudes are the same because "the gravitational force on the penguin is the same". I'm having trouble understanding this. I thought the buoyant force was equal to the weight of the fluid displaced. Weight depends on mass which depends on density. Therefore, due to the differing densities the buoyant force will be different in each case? Is this incorrect?

Similar threads

Replies
7
Views
3K
Replies
4
Views
2K
  • · Replies 3 ·
Replies
3
Views
1K
Replies
19
Views
2K
  • · Replies 16 ·
Replies
16
Views
1K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 9 ·
Replies
9
Views
2K
Replies
44
Views
4K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
170
Views
8K