How Do You Draw Cell Diagrams Correctly?

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    Cell Diagrams
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Discussion Overview

The discussion revolves around the correct method for drawing cell diagrams in electrochemistry, specifically focusing on the placement of electrolytes and the balancing of half-reactions. Participants explore the representation of oxidation and reduction processes in the context of a homework problem.

Discussion Character

  • Homework-related
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant suggests that electrolytes from each half-cell should be placed on opposite sides of the diagram.
  • Another participant proposes splitting the overall reaction into half-reactions to clarify the process.
  • A participant provides specific half-reaction equations but notes that they are not balanced, indicating the omission of electrons.
  • It is mentioned that V3+ is oxidized and VO2+ is reduced, with a suggestion that the stronger reducing agent should be placed on the left side of the diagram.
  • There is confusion expressed by a participant regarding the placement of VO2+ in the context of the diagram.
  • A participant acknowledges the assistance received and expresses that the discussion will help in future exam preparation.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the correct placement of components in the cell diagram, and there are competing views on how to balance the half-reactions and the significance of the reducing and oxidizing agents.

Contextual Notes

Some participants note the importance of balancing half-reactions, specifically mentioning the need to include electrons, which remains unresolved in the discussion.

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Homework Statement


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Homework Equations


The Attempt at a Solution



I always thought you put the electrolyte of one half cell on one side and the other electrolyte on the other side

The answer given is C.
But this includes VO2+ which is not in the initial eqn on the RHS?
 
Last edited:
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Try to split the reaction into half reactions.
 
borek said:
try to split the reaction into half reactions.

V3+ + H2O = VO2+ + 2H+
VO2+ + H2o = VO2+ + 2h+
 
They are not balanced yet (you ignored electrons), but you are on the right track.

Do you see why C?
 
Borek said:
They are not balanced yet (you ignored electrons), but you are on the right track.

Do you see why C?

Well V3+ is oxidised (reducing agent) and VO2+ is reduced (oxidising agent).
I think you are supposed to put the stronger reducing agent on the left side?
 
jsmith613 said:
I think you are supposed to put the stronger reducing agent on the left side?

Isn't it what they did?
 
Borek said:
Isn't it what they did?

...of course...I think I just get confused between VO2+ and VO2+.

...I guess though this will help me in exams as I will be more aware of what is going on...thanks for helping me :)
 

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