How is saturation pressure different than vapor pressure?

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SUMMARY

The discussion clarifies the distinction between vapor pressure and saturation pressure. Vapor pressure is defined as the pressure exerted by a substance during evaporation or sublimation at a specific temperature, calculable via the Antoine Equation. In contrast, saturation pressure refers to the pressure at which a substance has fully vaporized to its equilibrium state. The key difference lies in the system's equilibrium status, with saturation pressure assuming maximum pressure at the interface regardless of other system conditions.

PREREQUISITES
  • Understanding of the Antoine Equation for calculating vapor pressure
  • Knowledge of phase transitions, specifically evaporation and sublimation
  • Familiarity with thermodynamic equilibrium concepts
  • Basic grasp of pressure measurement techniques in gaseous systems
NEXT STEPS
  • Research the Antoine Equation and its applications in calculating vapor pressure
  • Explore thermodynamic equilibrium and its implications in phase transitions
  • Study the relationship between temperature and vapor pressure in various substances
  • Investigate methods for measuring saturation pressure in different systems
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Students and professionals in chemistry, chemical engineering, and environmental science who seek to deepen their understanding of phase behavior and pressure dynamics in substances.

pa5tabear
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I think I understand, but I want to make sure.

The vapor pressure of a substance is the pressure of the substance evaporating/sublimating at a given temperature and can be calculated using the Antoine Equation. This must be measured at the interface of the substance and atmosphere, or if the system is at equilibrium, it could be measured anywhere in the system.

The saturation pressure assumes that the substance has fully vaporized to its equilibrium point. It could be measured at any gaseous part of the system.

They are almost the same, right? The difference is just whether the system is at equilibrium?
 
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If I understand your question correctly - yes. We just assume pressure has its maximum possible value at the interface, no matter what is going on in other parts of the system. This is equivalent of assuming there is an equilibrium on the surface.
 

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