How to measure average thermal conductivity of a metallic material?

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    Thermodynamics
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SUMMARY

This discussion focuses on measuring the average thermal conductivity of metallic materials using a specific experimental setup. The method involves heating one end of a metal bar while cooling the other end with water, ensuring thermal insulation. The average thermal conductivity, denoted as K, is calculated using the equation K = (L / A(T1 - T2))(dQ/dt), where L is the distance between thermocouples, A is the cross-sectional area, and T1 and T2 are temperatures measured at two points. Accurate measurements require understanding heat loss through insulation and ensuring steady-state conditions before recording data.

PREREQUISITES
  • Understanding of heat conduction principles and the fundamental law of heat conduction.
  • Familiarity with thermocouples and their application in temperature measurement.
  • Knowledge of calorimetry for measuring heat transfer to water.
  • Basic proficiency in algebraic manipulation of equations related to thermal conductivity.
NEXT STEPS
  • Research the principles of heat conduction and the fundamental law of heat conduction.
  • Learn about the setup and calibration of thermocouples for accurate temperature measurement.
  • Study calorimetry techniques to quantify heat transfer in experiments.
  • Explore methods for ensuring steady-state conditions in thermal experiments.
USEFUL FOR

Researchers, materials scientists, and engineers involved in thermal analysis and materials testing will benefit from this discussion, particularly those focused on measuring thermal properties of metals.

zenterix
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TL;DR
How exactly does this experiment to measure average thermal conductivity of a metallic slab work?
Heat conduction is the transport of energy between neighboring volume elements in a material as a result of the temperature difference between them.

The "fundamental law of heat conduction", as it is called in the book I am reading, is a "generalization of the results of experiments on the linear flow of heat through a slab perpendicular to the faces".

Pictorially, such experiments do the following

1699738959320.png

The blue rectangular box represents a slab of a material of thickness ##\Delta x## and the area of the side faces is ##A##. One face is maintained at temperature ##T## and the other at ##T+\Delta T##.

The heat that flows perpendicular to the faces for a time ##t## is measured.

The same experiment is repeated by keeping the material the same and varying ##\Delta x## and ##A##.

These experiments lead to the following result

$$\frac{Q}{t} \propto A\frac{\Delta T}{\Delta x}\tag{1}$$

which is approximately true for finite ##\Delta T## and ##\Delta x## and rigorously true when these are infinitesimals.

In this limit, we obtain

$$\frac{dQ}{dt}=-KA\frac{dT}{dx}\tag{2}$$

where the ##dQ## is an inexact differential (I don't know how to write the correct symbol in latex).

The derivative ##dT/dx## is the temperature gradient, ##K## is the thermal conductivity.

My question is about measurement of thermal conductivity.

Here is the experiment for a metal.

The metal is made into the form of a bar, one end is heated electrically, the other end is cooled with a stream of water. The surface of the bar is thermally insulated.

Heat loss through the insulation is calculated by subtracting the rate at which heat enters the water from the rate at which electrical energy is supplied.

The equation used to determine the average thermal conductivity within the given temperature range is

$$K=\frac{L}{A(T_1-T_2)}\frac{dQ}{dt}\tag{3}$$

where again, ##dQ## is an inexact differential.

The temperature difference is measured with thermocouples at two places a distance ##L## apart.

Here is what I think happens

- The amount of heat provided during a certain time to one end of the metal is known (how does one control the amount of heat?). This is ##dQ/dt##.

- ##L## and ##A## are fixed

- The only thing measured is the "temperature difference". This temperature difference seems to be that between the two metallic faces.

However, it also seems that one somehow measures heat entering the water as well. How does one do this?

Does it involve also measuring the temperature difference of the water?
 
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zenterix said:
The only thing measured is the "temperature difference". This temperature difference seems to be that between the two metallic faces.
No. The temperature difference is the difference between the readings of the thermocouples that are placed distance ##L## apart. I wouldn't place the thermocouples at the ends of the block where the heat source and sink are because you are likely to get erroneous readings.
zenterix said:
Does it involve also measuring the temperature difference of the water?
Yes, you need to do some calorimetry to find out how much heat enters the water per unit time. The equation for ##K## assumes that no heat is lost as it travels from one end to the other.

Also, you should not record any measurements until you are sure that the steady state is reached. How are you going to figure out when this happens?
 

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