How to separate CO2 into C and O2

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SUMMARY

The discussion centers on methods to separate carbon dioxide (CO2) into carbon (C) and oxygen (O2). Key techniques mentioned include heating CO2 over a catalyst of iron-doped zeolite and hydrogen, which produces water and ethylene, and utilizing electrolysis of water to regenerate hydrogen and produce oxygen. The process requires significant energy, estimated at 393.5 kJ/mol, and is currently being explored by NASA for potential applications in space missions, particularly on Mars. Other methods discussed include biological processes like photosynthesis and chemical reactions involving sodium peroxide.

PREREQUISITES
  • Chemical thermodynamics, specifically energy requirements for reactions
  • Catalysis principles, including the role of iron-doped zeolite
  • Photosynthesis processes and their application in oxygen production
  • Electrolysis techniques for hydrogen and oxygen generation
NEXT STEPS
  • Research the Boudouard reaction for CO2 conversion to carbon and oxygen
  • Explore the use of iron-doped zeolite as a catalyst in chemical reactions
  • Investigate NASA's current projects on CO2 reduction for Mars missions
  • Learn about the energy requirements and efficiencies of electrolysis methods
USEFUL FOR

Chemists, environmental scientists, aerospace engineers, and anyone interested in carbon capture and conversion technologies.

  • #31
DrStupid said:
How about the Boudouard reaction as a second step:

1. 2 CO2 -> 2 CO + O2
2. 2 CO -> CO2 + C

Sure, if your goal is to produce carbon. The carbon would likely foul the catalyst though and since the Martian atmosphere has plenty of CO2 already, there is no advantage to the second step IMO. The design of the reactor might need to be such that this reaction is prevented from happening.
 
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  • #32
chemisttree said:
Sure, if your goal is to produce carbon.

According to the title of this thread it is.
 
  • #33
DrStupid said:
According to the title of this thread it is.

Of course it is but you were responding to my post which featured links where the final carbon-containing species was CO (as I indicated).
 
  • #34
In radiocarbon dating one reduces carbon dioxide e.g. with iron and hydrogen gas to elemental carbon. You could freeze out the water formed in that process from the hydrogen stream and separate it by electrolysis. Net result would be the analysis of carbon dioxide into carbon and oxygen.
 
  • #35
chemisttree said:
Of course it is but you were responding to my post which featured links where the final carbon-containing species was CO (as I indicated).

And because CO is only half the way to carbon I suggested a second step to complete the separation of CO2 into C and O2.
 
  • #36
DrStupid said:
And because CO is only half the way to carbon I suggested a second step to complete the separation of CO2 into C and O2.

Doh! You're right. That would address the OP's original question.
 

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