Is Total Angular Momentum Conserved in the Hydrogen Ion Molecule H₂⁺?

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SUMMARY

The discussion centers on the conservation of total angular momentum in the hydrogen ion molecule H₂⁺, as presented in Wolfgang Demtroder's book "Molecular Physics." The claim that total angular momentum is a constant quantum number is contested, with the argument that the nuclear potential in H₂⁺ is not spherically symmetric, thus violating conservation. Instead, it is noted that while total angular momentum is not conserved, quantities related to the axis of symmetry are conserved, aligning with Noether's theorem.

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  • Understanding of Noether's theorem
  • Familiarity with quantum mechanics concepts
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  • Basic comprehension of symmetry in physical systems
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  • Explore the concept of axial symmetry in molecular systems
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This discussion is beneficial for physicists, particularly those specializing in quantum mechanics and molecular physics, as well as students seeking to understand the implications of symmetry and conservation laws in molecular systems.

Jamister
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in the book Molecular Physics of Wolfgang Demtroder, he claims for hydrogen ion molecule ##H_2 ^+## the total angular momentum in absolute value is a constant quantum number. I never saw it any other book and I think it's wrong, because there is no reason for it and he doesn't prove it. here is what he says in the book:
1566508869929.png


what do you think?
 
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This all comes from Noether’s theorem. The nuclear potential in ##H_2^+## is not spherically symmetric, so the total angular momentum is not conserved. However, it is axially symmetric, so quantities associated with the axis of symmetry are conserved.
 
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