Incandescence and electronic excitation

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    Electronic Excitation
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Discussion Overview

The discussion centers around the phenomenon of incandescence and its relationship to electronic excitation in various materials, including conductors and insulators. Participants explore the underlying mechanisms and conditions that lead to incandescence, particularly in the context of thermal energy distribution and electronic states.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant notes that incandescence occurs in a wide variety of materials, questioning its relation to electronic excitation.
  • Another participant explains that at equilibrium, thermal energy is distributed among all degrees of freedom that are not "frozen," including electronic degrees of freedom at high temperatures, leading to emission across a broad spectrum.
  • A different participant raises a question about how insulators can exhibit incandescence despite their large energy gaps preventing electron excitation at lower temperatures.
  • It is mentioned that states are populated with a probability related to the Boltzmann factor, indicating that thermal electronic excitation can occur, particularly at elevated temperatures where it becomes significant enough for incandescence to be observed.

Areas of Agreement / Disagreement

Participants express differing views on the role of electronic excitation in incandescence, particularly concerning insulators. There is no consensus on how insulators can exhibit this effect given their electronic structure.

Contextual Notes

Some assumptions about the behavior of electronic states in different materials and the conditions under which incandescence occurs remain unresolved. The discussion also highlights the complexity of thermal energy distribution and its implications for various materials.

hokhani
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As far as I experienced, incandescence happens in a wide variety of materials no matter what a substance (conductor, insulator and so on) is. Does this effect is related to the electronic excitation? Could anyone please explain the reason of this effect?
 
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At equilibrium, the thermal energy is spread out into all degrees of freedom that are not "frozen" (i.e., for which there is enough energy to lead to a significant population of the excited states). For high enough T, that includes electronics degrees of freedom. In the solid state, electronic states usually constitute continua, such that emission is over a wide range of the electromagnetic spectrum.

You should look up blackbody radiation.
 
DrClaude said:
At equilibrium, the thermal energy is spread out into all degrees of freedom that are not "frozen" (i.e., for which there is enough energy to lead to a significant population of the excited states). For high enough T, that includes electronics degrees of freedom.
In an ideal insulator electrons can not pass the large gap by thermal energy and so there is no electron excitation. How does an insulator show this effect?
 
States are populated with a probability proportional to ##e^{-E/kT}##. There is always some thermal electronic excitation, even though it can be neglected in most cases. But there is always a point where the temperature is high enough that it is not negligible anymore, and the object will glow.
 

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