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Dimension of Phase Space of a rigid diatomic molecule is 10. Shouldn't it be 12?
The dimension of phase space for a rigid diatomic molecule is definitively 10, not 12. This conclusion arises because rotation along the internuclear axis is not possible, eliminating one of the three Euler angles required for orientation. Consequently, the system retains four angular degrees of freedom, in addition to three coordinates and three momenta associated with the center of mass motion.
PREREQUISITESPhysicists, chemists, and students studying molecular dynamics and phase space theory will benefit from this discussion.