Lewis dot structures of complex molecules

In summary, the conversation is about determining the electron dot structure of molecules A and B, which can be found in the link provided. The equations and attempts at a solution are also discussed, with a question about the correctness of the solution. The conversation also touches upon the possible charges of the atoms in the structures and whether the assignment requires neutral species.
  • #1
pugtm
18
0

Homework Statement


determine the electron dot structure of molecules a and b
http://session.masteringchemistry.com/problemAsset/1144353/2/MMAt.05.067.jpg

Homework Equations



The Attempt at a Solution


A)

::O: H
| |
H-C=N-HB)
H
| ..
H-C-N=C=O::
|
H

I am not at all sure this is correct and the software that accepts answers for my school agrees with that assesment, any assistance will be greatly appreciated
 
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  • #2
Your first answer has a single bond between the carbon and the oxygen. That oxygen also has six other electrons around it. Would that result in the oxygen having a charge? You also show the enamine (with friends like that, who needs enamines?) nitrogen having four bonds to it. What would the charge be for that? Does your assignment want you to postulate neutral species? I'm betting it does.
 
  • #3
.

I would first like to commend you for attempting to determine the Lewis dot structures of molecules A and B on your own. This is an important skill in chemistry and it will help you understand the electronic structure of molecules better. However, I would like to point out a few things about your proposed structures.

Firstly, in molecule A, the nitrogen atom should have a lone pair of electrons, represented by two dots, instead of a single bond. This is because nitrogen typically forms three bonds and has one lone pair of electrons. Additionally, the carbon atom should have a double bond with nitrogen, represented by four dots, instead of a single bond. This is because carbon can form four bonds and in this case, it is forming a double bond with nitrogen.

In molecule B, the carbon atom should not have a double bond with nitrogen. Instead, it should have a single bond with nitrogen and a double bond with oxygen. This is because carbon typically forms four bonds and in this case, it is forming a single bond with nitrogen and a double bond with oxygen.

Based on these corrections, the correct Lewis dot structures for molecules A and B are:

A) H
| ..
H-C=N-H
| |
::O:H

B) H
| ..
H-C-N=O::
|
::O:H

I hope this helps clarify any confusion and helps you in your future chemistry studies. Keep up the good work!
 

1. What is a Lewis dot structure?

A Lewis dot structure is a diagram that represents the valence electrons and bonding in a molecule. It consists of the element's symbol in the center, surrounded by dots that represent the valence electrons.

2. How do you determine the number of valence electrons in a complex molecule?

To determine the number of valence electrons, you can refer to the periodic table. The group number of the element indicates the number of valence electrons it has. For complex molecules, you can also sum up the valence electrons of each individual atom.

3. What is the purpose of drawing Lewis dot structures for complex molecules?

Lewis dot structures help us understand the bonding and electron distribution in a molecule. They also aid in predicting the molecule's shape, polarity, and reactivity.

4. How do you draw a Lewis dot structure for a complex molecule?

To draw a Lewis dot structure, follow these steps:
1. Count the total number of valence electrons in the molecule.
2. Determine the central atom and connect each atom to it with single bonds.
3. Distribute the remaining electrons to each atom, giving octets (except for hydrogen, which only needs 2 electrons).
4. If there are not enough electrons for each atom to have an octet, try double or triple bonds.
5. Check for any formal charges and make adjustments if necessary.

5. Are Lewis dot structures always an accurate representation of a molecule's electron distribution?

No, Lewis dot structures are not always an accurate representation of a molecule's electron distribution. They do not take into account the actual shape of the molecule or the presence of lone pairs of electrons. Additionally, they do not account for resonance structures, which are multiple ways of drawing a molecule that have the same distribution of electrons.

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