Magnetism of Solids: Homework Solutions for Fe2+

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Homework Help Overview

The discussion revolves around the magnetic properties of solids, specifically focusing on the Fe2+ ion in a sample that includes MgO. Participants are exploring the relationship between magnetic susceptibility, temperature, and the contributions of different materials to the overall magnetic moment.

Discussion Character

  • Exploratory, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants are attempting to understand how to treat the sample's magnetic properties, particularly in relation to the temperature-independent susceptibility of MgO and the temperature-dependent behavior of Fe2+. Questions are raised about the implications of plotting magnetic moment versus temperature and how to interpret the combined effects of MgO and Fe.

Discussion Status

Some participants are providing guidance on considering the shapes of the magnetic moment curves for MgO and Fe separately, as well as their combined effect. There is an ongoing exploration of how to calculate the mass ratio and the contributions of each component to the overall magnetic moment, but no consensus has been reached on the specific methods to apply.

Contextual Notes

Participants are discussing the implications of temperature on magnetic moments and the need to clarify the role of volume in their calculations. There is an acknowledgment of the complexity introduced by the presence of both MgO and Fe in the sample.

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Homework Statement


N0Mdlnt.png


2. Homework Equations


##\mathcal{X}=\frac{\mu^2_BNg^2_j}{3k_BT}J(J+1)=\frac{C}{T}##

##M=\mathcal{X}H##

The Attempt at a Solution


[/B]
##Fe^{2+}## has a value 4 of J from hunds rules.

So I know what the curie factor for iron is

##M=\frac{m}{V}=\frac{HC}{T}##

##m=\frac{HVC}{T}##

I don't know how I am supposed to treat the sample, assuming that MgO has a temp independent, diamagnetic susceptibility means that the changing magnetic moment is just from the iron but I am not sure how to use this?
 
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You will need to think around the subject for a bit to seek inspiration.
i.e. if you were to plot a graph of magnetic moment vs temp - what sort of curve would the MgO alone get you? What sort of curve for Fe aone? What sort of shape is the combined curve likely to be?
What happens to the magnetic moment of the sample as the temperature increases? Describe in terms of the relative moments of the MgO and the Fe.
 
Simon Bridge said:
You will need to think around the subject for a bit to seek inspiration.
i.e. if you were to plot a graph of magnetic moment vs temp - what sort of curve would the MgO alone get you? What sort of curve for Fe aone? What sort of shape is the combined curve likely to be?
What happens to the magnetic moment of the sample as the temperature increases? Describe in terms of the relative moments of the MgO and the Fe.

Drawing the graph helped, thanks, the combined graph goes as 1/T and tends towards the magnetic moment of MgO as T increases.

What do you mean by "Describe in terms of the relative moments of the MgO and the Fe."?

Also what should I try to be working out, the susceptibility of Mg0, the volumes?

The equation for the curve I have is

##m_{total}=HV_{FE}\frac{C}{T}+HV_{MgO}\mathcal{X}_{MgO}##

##m_{total}=H(V_{FE}\frac{C}{T}+V_{MgO}\mathcal{X}_{MgO})##
 
You are supposed to be working out the mass ratio...
 
Simon Bridge said:
You are supposed to be working out the mass ratio...
I'm aware of that but I can't see how to get to it, I have a formula with volume in it due to the magnetization/magnetic moment relation which I don't know how to deal with.
 

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