SchroedingersLion said:
So in general a mixed state can't be thought as a statistical mixture of pure states, BUT if I have a certain experimental setup that creates state |i> with probability p and state |j> with probability (1-p) I have to describe the system as a mixed state. Is this correct?
Sorry for coming to this late - I've been traveling over Summer with somewhat random internet access (perhaps my connection was in a mixed state of 'off' and 'on').
Anyway, you've had some good answers to your questions so far and I'm not sure I can add very much - and most of what I'm going to write is simply a restatement of what others have said. I tend to be a bit of a windbag so I hope you get something of value from my verbal excess
In general a mixed state can indeed be thought of as a statistical mixture of pure states - but only because it's formally indistinguishable from that. For example, suppose I have the mixed state of a spin-1/2 particle in a mixed state described by $$ | \psi \rangle = \frac 1 2 |z+ \rangle \langle z+ | + \frac 1 2 |z- \rangle \langle z- | $$ then I can interpret that as having been prepared as the pure state ##| z+ \rangle## with probability 1/2 and the pure state ##|z- \rangle## with probability 1/2. So basically having been prepared as an 'up ' or 'down' eigenstate of spin-z with equal probability.
However, the actual preparation procedure might have been to prepare the particle with equal probability in the state ##| x+ \rangle## or ##|x- \rangle##, that is, in one of the eigenstates of spin-x chosen at random.
The thing is both preparation procedures lead to the same quantum state. So yes, it can be thought of as a statistical mixture of the pure spin-z eigenstates, but it can also be thought of as a statistical mixture of the spin-x eigenstates. In fact it can be thought of as a statistical mixture of the spin-##\theta## eigenstates - where ##\theta## is any arbitrary direction.
There's just no way to tell from the formalism the difference between them. So even though the initial preparation procedure might have been to choose eigenstates of spin-z at random, it wouldn't actually be 'wrong' to think of the state as having been prepared by choosing spin-x eigenstates at random. There's no way to experimentally distinguish between the two preparation procedures.
We can set this up operationally by having Clive receive a spin-1/2 particle from Alice and a spin-1/2 particle from Bob (let's imagine the 2 particles delivered in a nice presentation case such that Clive doesn't know which is from Alice and which is from Bob). Alice has chosen the state of her particle to be one of the spin-z eigenstates at random, Bob has chosen the state of his particle to be one of the spin-x eigenstates at random. Clive's job is to tell which particle has come from Bob and which particle has come from Alice. There is nothing Clive can do that would give him a better probability of identifying the particles that is better than guessing.
So in a nutshell - if it helps to think of a density operator as a prepared statistical mixture of particular pure states then it's not 'wrong' to do so - even though the actual preparation might have been very different. You'll get the same answers because there's no way to tell the specific 'preparation procedure' from a given density operator. In general the description of a density operator in terms of pure states is not unique.
To give another example the classic entangled singlet state consists of 2 spin-1/2 particles. Let's suppose I give you just one of these particles. Now the density operator you would use to determine the results of measurements on your particle is mathematically identical to the density operator you'd need if I simply gave you an unentangled spin-1/2 particle prepared in a randomly chosen eigenstate of spin-z (for example). Once again we can think of this operationally - if I gave you a spin-1/2 particle and told you it was (a) either one from an entangled pair or (b) in an eigenstate of spin-z chosen at random, you would not be able to do any better than guessing as to whether it was preparation (a) or (b).
Can I give you a better insight into the physical meaning of the density operator? Not really, I'm afraid. It's a great mathematical tool and very important but I confess I don't have a really good way to describe what it is in a 'physical' sense because it's not really all that clear to me either
