One-dimensional potential well problem

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Homework Help Overview

The discussion revolves around a one-dimensional potential well problem in quantum mechanics, specifically addressing the behavior of a particle in a potential defined by infinite barriers and a finite potential outside the well. The original poster is attempting to derive the wavefunction and analyze the energy states of the particle within the potential well.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster discusses the form of the wavefunction in different regions of the potential and questions their assumptions regarding energy and wavefunction continuity. They express confusion over the derived equations and the implications of negative values in their calculations.

Discussion Status

Participants are actively engaging with the original poster's reasoning, offering corrections and alternative perspectives on the wavefunction formulation. Some participants suggest reconsidering the boundary conditions and the nature of the wavefunctions, while others provide external resources that may aid understanding.

Contextual Notes

The original poster is working under the constraints of a homework assignment, which may impose specific requirements for the wavefunction and energy calculations. There is an ongoing exploration of the implications of the potential well's boundaries on the wavefunctions.

Ruddiger27
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My head's melting right now, because I've been stuck on this for the past 6 hours.
There's a particle of mass moving in a potential well where
V(x) = infinity at x<0
V(X)=0, 0<x<a
V(x)= Vo, x>a

Vo>0
E<Vo

I'm assuming that the wavefunction at x<0 is 0, since there's an infinite potential there. The energy inside the potential well is just the kinetic energy, =(Hk)^2/2m, where H=h/2pi, so the wavefunction should be of the form
psi= Aexp(-ikx )
Now outside the well, at x>a, the energy should be E= Vo-Ek because the particle is bound in the well. We then get psi=Bexp(-Tx), where T is k with (Vo-E) instead of E.
Am I wrong in assuming this? When I try to find the radius using
X^2 + y^2 = R^2, where x=k=a*sqrt(2mE)/H and y=ai*(sqrt(2m(Vo-E))/H
I get out a negative radius.
Please help me see what I've done wrong, I'm sure I've got the energy value on the finite potential side wrong, but I can't see how.
 
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Haven't gone through your entire question to know if this is the only mistake, but I believe you made a mistake determining psi in the well.

When you solve the differential equation you should get a couple exponentials...something like

psi=A*exp(ikx)+B*exp(-ikx).

Remember these are complex exponentials so they don't blow up at infinity and you can't eliminate terms like with real exponentials.

Now your boundary conditions require that psi=0 for x</= 0, so plugging in 0 for x we get A+B=0, and hence A=-B, and psi is some sort of sine wave of the form
psi=A(exp(ikx)-exp(-ikx))

I haven't gone through the rest of your problem, and I'm not sure what radius you are referring to at the end.
 
The radius comes in when we look at the wavefunctions across x=a, where they should be continuous, so psi1=psi2 and dpsi1/dx=dpsi2/dx. I have to divide one by the other to get a solution in the form -y=xcot(x), then rearrange the circle equation to get y, sub it in and the intersection gives the solution.
 
Ok thanks, you've really helped me out, the website was especially helpful.
 

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