Partial derivatives in thermodynamics

AI Thread Summary
The discussion centers on the differentiation of functions of multiple variables, particularly in the context of thermodynamics. The user expresses confusion about differentiating functions where some variables depend on others, specifically in expressions involving partial derivatives. They seek formal theorems related to these types of derivatives and note that many thermodynamics textbooks cover this topic. A suggestion is made to refer to a specific chapter from a thermodynamics resource found online for further clarification. The conversation highlights the importance of understanding partial derivatives in thermodynamic equations.
maxBrunsfeld
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in basic multivariate calculus, i never learned about differentiating functions of multiple variables which are also functions of each other. i.e.

\frac{d}{d x_1} \left[ f(x_1, x_2, x_3) \right]

where x_1 = g(x_2, x_3)

studying thermodynamics right now, I'm encountering into expressions like

\mu = - \left(\frac{\partial U}{\partial S} \right)_{N,V} \left( \frac{\partial S}{\partial N} \right)_{U,V}

where some particular variables are held fixed, but others are not. I'm wondering if there are formal theorems relating to partial derivatives like these or if you guys have any knowledge specifically relating to them.
 
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maxBrunsfeld said:
i'm wondering if there are formal theorems relating to partial derivatives like these

All the thermodynamics textbooks that I've seen, spend some time discussing them early on.

If yours doesn't, you might try downloading Chapter 2 from

http://www.astro.uvic.ca/~tatum/thermod.html

which I found by doing a Google search for "partial derivatives in thermodynamics".
 
thank you. that's exactly the kind of thing i was looking for. sorry if that was so easy to find that it didn't warrant asking the forum.
 
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