Perturbation Theory - expressing the perturbation

Zero1010
Messages
40
Reaction score
2
Homework Statement
Specify the perturbation for the Coulomb model of hydrogen.
Relevant Equations
##V(x) =

\begin{cases}

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{if } 0<r \leq 0 \\

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{if } r > 0

\end{cases} ##
Hi,

I just need someone to check if I am on the right track here

Below is a mutual Coulomb potential energy between the electron and proton in a hydrogen atom which is the perturbed system:

##V(x) =
\begin{cases}
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{for } 0<r \leq 0 \\
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{for } r > 0
\end{cases} ##

Where e = mag of electron charge, B = a constant length, ##4\pi\epsilon_{0}## = permittivity of free space

Using this I need to specify the perturbation of the system.

Since V(x) is the perturbed system is the total perturbation the sum of both these functions across the length?

In which case I get:

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} + (- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r})##

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}(\frac{b}{r^{2}} + \frac{1}{r})##

I just want to check if this is the correct way to go about this?

Thanks in advance.
 
Last edited:
Physics news on Phys.org
I don't understand the potential you are looking at. Usually for the hydrogen atom you just use the simple Coulomb potential. What does the first line mean? ##0<r \leq 0## is self-contradictory, because ##r>0## already implies that ##r \neq 0##.
 
  • Like
Likes Zero1010
Thanks for the reply.

Sorry that's my typo it should be:

##0 \lt r \leq b##

and the second one should be

##r \gt b##

Also in the question it says to suppose there is a deviation from Coulombs law at very small distances (even though there is no evidence for it)
 
Zero1010 said:
Homework Statement:: Specify the perturbation for the Coulomb model of hydrogen.
Relevant Equations:: ##V(x) =

\begin{cases}

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{if } 0<r \leq 0 \\

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{if } r > 0

\end{cases} ##

Hi,

I just need someone to check if I am on the right track here

Below is a mutual Coulomb potential energy between the electron and proton in a hydrogen atom which is the perturbed system:

##V(x) =
\begin{cases}
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{for } 0<r \leq 0 \\
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{for } r > 0
\end{cases} ##

Where e = mag of electron charge, B = a constant length, ##4\pi\epsilon_{0}## = permittivity of free space

Using this I need to specify the perturbation of the system.

Since V(x) is the perturbed system is the total perturbation the sum of both these functions across the length?

In which case I get:

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} + (- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r})##

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}(\frac{b}{r^{2}} + \frac{1}{r})##

I just want to check if this is the correct way to go about this?

Thanks in advance.
You should be subtracting the Coulomb potential in ##\delta\hat H##.
 
  • Like
Likes vanhees71 and Zero1010
Thread 'Help with Time-Independent Perturbation Theory "Good" States Proof'
(Disclaimer: this is not a HW question. I am self-studying, and this felt like the type of question I've seen in this forum. If there is somewhere better for me to share this doubt, please let me know and I'll transfer it right away.) I am currently reviewing Chapter 7 of Introduction to QM by Griffiths. I have been stuck for an hour or so trying to understand the last paragraph of this proof (pls check the attached file). It claims that we can express Ψ_{γ}(0) as a linear combination of...
Back
Top