Undergrad Why Do Different Primitive Unit Cells for Diamond Look So Different?

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SUMMARY

The discussion centers on the construction of primitive unit cells for diamond, which is characterized by a face-centered cubic (fcc) lattice and a basis of two carbon atoms. Two distinct variants of the primitive unit cell are presented, one occupying 1/4 of the conventional cell volume and the other 1/8. The confusion arises from the visual and structural differences between these two representations, despite both containing two whole atoms in the lattice. The participant seeks clarification on why these primitive unit cells appear so different and how they can fulfill the definition of a unit cell.

PREREQUISITES
  • Understanding of face-centered cubic (fcc) lattice structures
  • Knowledge of primitive unit cells in crystallography
  • Familiarity with the concept of basis in crystal structures
  • Basic principles of unit cell volume calculations
NEXT STEPS
  • Research the differences between primitive and conventional unit cells in crystallography
  • Explore the implications of lattice points in unit cell definitions
  • Learn about the construction of unit cells for various crystal structures
  • Investigate the role of tetrahedral coordination in diamond structures
USEFUL FOR

Students and researchers in materials science, crystallography, and solid-state physics who are studying diamond structures and unit cell configurations.

Porkaborg
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TL;DR
Primitive unit cell of diamond, great confusion.
Hi guys , I want to construct a primitive unit cell for diamond, which is made of a fcc lattice and a basis of 2 carbons atoms. I know that a primitive unit cell isn't unique but the two variants I get are drastically different . As far as I can see they both include 2 whole atoms/points in the lattice, however one of them occupies 1/4 of the conventional-cell volume, and the other occupies 1/8 of the conventional-cell volume.

When I couldn't get further in reasoning, I tried googling it and found both versions listed as primitive unit cells for diamond. But I am still confused why they look so very different.
(The left picture doesn't include rest of the atoms for some reason but they are there before creating the primitive unit cell)

Skærmbillede 2019-10-04 kl. 22.48.17.png
Skærmbillede 2019-10-04 kl. 22.45.25.png


I hope someone can point out the difference , or pinpoint why I may be confused, please comment if I need to add some additional info.
 
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How do you want to fill space with only translated copies of a tetrahedron?
 
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I guess I can't , which is needed to fulfill the definition of a unitcell. Thanks a lot DrDu!. Upon looking some more at it , the tetrahedron also doesn't include a single lattice point which it is supposed to do to be a primitive unit cell.
 

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