Problem involving Negative Temperature

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Homework Help Overview

The discussion revolves around a problem involving negative temperature in a statistical mechanics context, specifically focusing on the partition function and population inversion conditions in a two-level system. Participants explore the implications of these conditions on the energy states and total energy of the system.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Problem interpretation, Assumption checking

Approaches and Questions Raised

  • Participants examine the relationship between particle populations in different energy states and the conditions for population inversion. They raise questions about deriving inequalities for total energy based on these conditions and explore how to express energy in terms of particle numbers and energy levels.

Discussion Status

The discussion is active, with participants providing guidance on how to approach the problem of finding energy ranges under the condition of negative temperature. There is an ongoing exploration of inequalities involving total energy, particle numbers, and energy levels, with some participants questioning the necessity of including temperature in their formulations.

Contextual Notes

Participants note that the problem does not provide explicit definitions for temperature or total energy, leading to various interpretations and approaches to derive inequalities. The constraints of the problem, such as the requirement for population inversion and the implications of negative temperature, are central to the discussion.

  • #31
tanaygupta2000 said:
how do I find the equilibrium temperature of these two ?
Despite my having been able to figure out the first part, the subject is something I've never studied, so just guessing here... won't equilibrium be when A and B have the same total energies?
 
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  • #32
haruspex said:
Despite my having been able to figure out the first part, the subject is something I've never studied, so just guessing here... won't equilibrium be when A and B have the same total energies?
Sir but A is having positive temperature while B is having negative temperature.
 
  • #33
tanaygupta2000 said:
Sir but A is having positive temperature while B is having negative temperature.
Yes... whatever that really means. But I still don't see how they can be in equilibrium unless the energy is shared equally. Then again, it's not a subject I claim to know anything about.
 
  • #34
tanaygupta2000 said:
(2.) If A and B are two subsystems of the given system, each having N/2 particles, and A having energy E(A) = Nε/8 and B having energy E(B) = 5Nε/8, which of these has positive/negative temperature?
If B has N/2 particles, then the maximum possible energy for system B is when all N/2 particles have the energy ε. Thus, the maximum energy for B is Nε/2. But, E(B) is given to be 5Nε/8 which is greater than the maximum.

I wonder if the problem meant E(A) = NAε/2 and E(B) = 5NBε/8, where NA = NB = N/2.

Anyway, I agree with @haruspex that the energy of the two subsystems should be equal when the subsystems are in equilibrium.
 
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  • #35
TSny said:
If B has N/2 particles, then the maximum possible energy for system B is when all N/2 particles have the energy ε. Thus, the maximum energy for B is Nε/2. But, E(B) is given to be 5Nε/8 which is greater than the maximum.

I wonder if the problem meant E(A) = NAε/2 and E(B) = 5NBε/8, where NA = NB = N/2.

Anyway, I agree with @haruspex that the energy of the two subsystems should be equal when the subsystems are in equilibrium.
Sir but how do I solve the third part of the question? What can I say about the equilibrium temperature?
 
  • #36
tanaygupta2000 said:
Sir but how do I solve the third part of the question? What can I say about the equilibrium temperature?
See your post #5. You can get T from E.
 
  • #37
TSny said:
See your post #5. You can get T from E.
We deduced, Nε/2 < E < Nε
Since E = Nε/(1+e(ε/kT))
=> Nε/2 < Nε/(1+e(ε/kT)) < Nε
=> 1/2 < 1/(1+e(ε/kT)) < 1
=> 2 > 1+e(ε/kT) > 1
=> 1 > e(ε/kT) > 0
=> 0 > ε/kT > -∞
=> 0 > 1/T > -∞
Is this correct ?
 
  • #38
Once the two subsystems A and B are in equilibrium with each other, you can treat the whole system as one system in a state of thermal equilibrium. So, you can apply the relation E = Nε/(1+e(ε/kT)) to the whole system. You know the value of E for the whole system. Therefore, you can solve the relation for T to get the equilibrium temperature of the system.
 
  • #39
TSny said:
Once the two subsystems A and B are in equilibrium with each other, you can treat the whole system as one system in a state of thermal equilibrium. So, you can apply the relation E = Nε/(1+e(ε/kT)) to the whole system. You know the value of E for the whole system. Therefore, you can solve the relation for T to get the equilibrium temperature of the system.
Using E = Nε/(1+e(ε/kT)), I am getting T = (ε/k) /ln(Nε/E - 1)

Substituting E = Nε/8 + 5Nε/8 = 3Nε/4
=> T = (ε/k) /ln(1/3) = (ε/k) /(-1.098) = -0.91ε/k

Hence the system as a whole is having NEGATIVE TEMPERATURE.
 
  • #40
tanaygupta2000 said:
Using E = Nε/(1+e(ε/kT)), I am getting T = (ε/k) /ln(Nε/E - 1)

Substituting E = Nε/8 + 5Nε/8 = 3Nε/4
=> T = (ε/k) /ln(1/3) = (ε/k) /(-1.098) = -0.91ε/k

Hence the system as a whole is having NEGATIVE TEMPERATURE.
Yes. That looks right if the total energy is 3Nε/4.

However, as I mentioned earlier, I don't believe it's possible for system B to have an initial energy of 5Nε/8. The maximum possible energy of B (or A) is (N/2)ε, since B has only N/2 particles.
 

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