Problem involving Negative Temperature

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SUMMARY

The discussion revolves around calculating the range of total energy for a system exhibiting negative temperature, specifically under the condition of population inversion where n1 < N/2. The partition function is defined as Z = 1 + e(-ε/kT), leading to the expressions for particle populations in different energy states. The final conclusion establishes that the total energy E must satisfy the inequality Nε/2 < E < Nε, indicating that the total energy is bounded between these values when considering the constraints of the system.

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  • #31
tanaygupta2000 said:
how do I find the equilibrium temperature of these two ?
Despite my having been able to figure out the first part, the subject is something I've never studied, so just guessing here... won't equilibrium be when A and B have the same total energies?
 
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  • #32
haruspex said:
Despite my having been able to figure out the first part, the subject is something I've never studied, so just guessing here... won't equilibrium be when A and B have the same total energies?
Sir but A is having positive temperature while B is having negative temperature.
 
  • #33
tanaygupta2000 said:
Sir but A is having positive temperature while B is having negative temperature.
Yes... whatever that really means. But I still don't see how they can be in equilibrium unless the energy is shared equally. Then again, it's not a subject I claim to know anything about.
 
  • #34
tanaygupta2000 said:
(2.) If A and B are two subsystems of the given system, each having N/2 particles, and A having energy E(A) = Nε/8 and B having energy E(B) = 5Nε/8, which of these has positive/negative temperature?
If B has N/2 particles, then the maximum possible energy for system B is when all N/2 particles have the energy ε. Thus, the maximum energy for B is Nε/2. But, E(B) is given to be 5Nε/8 which is greater than the maximum.

I wonder if the problem meant E(A) = NAε/2 and E(B) = 5NBε/8, where NA = NB = N/2.

Anyway, I agree with @haruspex that the energy of the two subsystems should be equal when the subsystems are in equilibrium.
 
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  • #35
TSny said:
If B has N/2 particles, then the maximum possible energy for system B is when all N/2 particles have the energy ε. Thus, the maximum energy for B is Nε/2. But, E(B) is given to be 5Nε/8 which is greater than the maximum.

I wonder if the problem meant E(A) = NAε/2 and E(B) = 5NBε/8, where NA = NB = N/2.

Anyway, I agree with @haruspex that the energy of the two subsystems should be equal when the subsystems are in equilibrium.
Sir but how do I solve the third part of the question? What can I say about the equilibrium temperature?
 
  • #36
tanaygupta2000 said:
Sir but how do I solve the third part of the question? What can I say about the equilibrium temperature?
See your post #5. You can get T from E.
 
  • #37
TSny said:
See your post #5. You can get T from E.
We deduced, Nε/2 < E < Nε
Since E = Nε/(1+e(ε/kT))
=> Nε/2 < Nε/(1+e(ε/kT)) < Nε
=> 1/2 < 1/(1+e(ε/kT)) < 1
=> 2 > 1+e(ε/kT) > 1
=> 1 > e(ε/kT) > 0
=> 0 > ε/kT > -∞
=> 0 > 1/T > -∞
Is this correct ?
 
  • #38
Once the two subsystems A and B are in equilibrium with each other, you can treat the whole system as one system in a state of thermal equilibrium. So, you can apply the relation E = Nε/(1+e(ε/kT)) to the whole system. You know the value of E for the whole system. Therefore, you can solve the relation for T to get the equilibrium temperature of the system.
 
  • #39
TSny said:
Once the two subsystems A and B are in equilibrium with each other, you can treat the whole system as one system in a state of thermal equilibrium. So, you can apply the relation E = Nε/(1+e(ε/kT)) to the whole system. You know the value of E for the whole system. Therefore, you can solve the relation for T to get the equilibrium temperature of the system.
Using E = Nε/(1+e(ε/kT)), I am getting T = (ε/k) /ln(Nε/E - 1)

Substituting E = Nε/8 + 5Nε/8 = 3Nε/4
=> T = (ε/k) /ln(1/3) = (ε/k) /(-1.098) = -0.91ε/k

Hence the system as a whole is having NEGATIVE TEMPERATURE.
 
  • #40
tanaygupta2000 said:
Using E = Nε/(1+e(ε/kT)), I am getting T = (ε/k) /ln(Nε/E - 1)

Substituting E = Nε/8 + 5Nε/8 = 3Nε/4
=> T = (ε/k) /ln(1/3) = (ε/k) /(-1.098) = -0.91ε/k

Hence the system as a whole is having NEGATIVE TEMPERATURE.
Yes. That looks right if the total energy is 3Nε/4.

However, as I mentioned earlier, I don't believe it's possible for system B to have an initial energy of 5Nε/8. The maximum possible energy of B (or A) is (N/2)ε, since B has only N/2 particles.
 

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