To calculate P(A ∪ B) - P(A ∩ B) with given probabilities P(A) = 0.7 and P(B) = 0.9, the formula P(A ∪ B) = P(A) + P(B) - P(A ∩ B) is utilized. By rearranging, P(A ∪ B) - P(A ∩ B) simplifies to P(A) + P(B) - 2P(A ∩ B). To maximize this expression, minimizing P(A ∩ B) is essential, leading to the conclusion that P(A ∩ B) must equal 0.6 when P(A ∪ B) is set to its maximum of 1. Ultimately, the calculated value of P(A ∪ B) - P(A ∩ B) is 0.4.