Quantum - Postulate of getting specific momentum p = |A_p|^2

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Homework Help Overview

The discussion revolves around the postulates of quantum mechanics, specifically focusing on the relationship between wavefunctions and their coefficients in momentum space, denoted as A_p. Participants explore the implications of defining P(p) = |A_p|^2 as a postulate and question the foundational aspects of this relationship.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants examine the derivation of A_p and its connection to probability density, questioning the nature of postulates in quantum mechanics. They discuss the implications of different summation indices in wavefunction conjugates and the equivalence of various postulates.

Discussion Status

The conversation is ongoing, with participants actively questioning the definitions and relationships between postulates. Some guidance has been offered regarding the mathematical expressions involved, but no consensus has been reached regarding the interpretation of these postulates.

Contextual Notes

There is mention of potential confusion stemming from notes that state both the integral of the wavefunction and the sum of |A_p|^2 as postulates, leading to questions about their equivalence and the necessity of both in the context of quantum mechanics.

laser
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The first equation states that every wavefunction can be written as a sum of wavefunctions of definite momentum, with A_p being defined as the coefficients in the expansion such that when you take the |wavefunction|^2 it equals 1 - fine.

We then multiply by the wavefunction conjugate and integrate, and using some Kronecker delta trickery we get an expression for A_p. - I'm also okay with this.

But then we say that P(p) = |A_p|^2 is a postulate... From my experience in maths/physics, postulates should be "facts". But here we see that A_p came from somewhere... why are the coefficients in the expansion related to the probability of finding a certain momentum? Is this just experimentally observed and we take it to be true?

Please let me know how you think about this, as I feel like I am thinking of the notion of a "postulate" wrongly.
 
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laser said:
But here we see that A_p came from somewhere... why are the coefficients in the expansion related to the probability of finding a certain momentum?
You have
$$\psi(x)=\sum_l A_l ~\psi_l(x)$$ It follows that $$\psi^*(x)=\sum_m A_m^* ~\psi_m^*(x)$$Now suppose you consider $$\int_0^L \psi(x)\psi^*(x)dx~,$$ substitute from above and use some more Kronecker delta trickery. What do you get?
 
Firstly, I am not sure why you changed the subscripts when going to the wavefunction conjugate.

Also, the equation you asked me to consider is the same one in my image! So I will get A_m. But I don't see how that answers my question.
 
laser said:
Firstly, I am not sure why you changed the subscripts when going to the wavefunction conjugate.
Because they are two different summations and anyway the indices are dummy.
laser said:
Also, the equation you asked me to consider is the same one in my image! So I will get A_m. But I don't see how that answers my question.
It is not the same. Take a second careful look. Like I said, what happens when you substitute the summations with two different indices in the equation that I asked you to consider.
 
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kuruman said:
Because they are two different summations and anyway the indices are dummy.

It is not the same. Take a second careful look. Like I said, what happens when you substitute the summations with two different indices in the equation that I asked you to consider.
Ah okay I see. You get the sum over m of |A_m|^2
Screenshot_2.png

which is equal to the above image.

As it turns out, the above image is also equal to the probability density over all the space = 1! (from another postulate)

This leads to another question: why is |A_p|^2 = probability density a postulate as well as the |wavefunction|^2 = probability density? Surely just one of them being a postulate is enough!
 
Last edited:
laser said:
This leads to another question: why is |A_p|^2 = probability density a postulate as well as the |wavefunction|^2 = probability density? Surely just one of them being a postulate is enough!
The postulate is
$$\int_0^L \psi(x)\psi^*(x)dx=1.\tag{1}$$
Please provide the exact statement of the problem as was given to you and how "postulate" is mentioned in it. Note that $$\sum_p |A_p|^2=1$$ is another way of saying the same thing as equation (1).
 
kuruman said:
The postulate is
$$\int_0^L \psi(x)\psi^*(x)dx=1.\tag{1}$$
Please provide the exact statement of the problem as was given to you and how "postulate" is mentioned in it. Note that $$\sum_p |A_p|^2=1$$ is another way of saying the same thing as equation (1).
I'm just reading some notes, it says that equation (1) is a postulate, but it also said that the sum of |A_p|^2 = 1 is also a postulate. Probably just a mistake in the notes, as either postulate can be used to derive the other!

Source: https://oyc.yale.edu/sites/default/files/notes_quantum_9.pdf page 21 equation (34)
 
I wouldn't worry about it.
 
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