Relation between k and group velocity in bands

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SUMMARY

The discussion centers on the relationship between wave vector conservation and group velocity in electronic transitions within crystals. It emphasizes that during indirect transitions, such as from the top of the valence band to the bottom of the conduction band, the group velocity and momentum of electrons remain unchanged, necessitating the involvement of phonons to conserve crystal momentum. The distinction between crystal momentum and true momentum is critical in understanding these transitions.

PREREQUISITES
  • Understanding of wave vector in solid-state physics
  • Knowledge of electronic band structure, specifically valence and conduction bands
  • Familiarity with phonon interactions in crystal lattices
  • Concept of crystal momentum versus true momentum
NEXT STEPS
  • Study the principles of conservation of crystal momentum in solid-state physics
  • Explore the role of phonons in electronic transitions
  • Learn about indirect transitions in semiconductor materials
  • Investigate the implications of group velocity in band theory
USEFUL FOR

Physicists, materials scientists, and students studying solid-state physics, particularly those interested in electronic properties of crystals and semiconductor physics.

hokhani
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In transitions in the crystals we always use conservation of wave vector of electron, not electron momentum conservation. For example in an indirect transition from top of valence band to bottom of conduction band, the group velocity of electron and hence its momentum would not change (it is zero at the two points). so why do we need a phonon to conserve the momentum?
 
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Because of conservation of the crystal momentum aka wavevector? Note that the crystal momentum is distinct from the true momentum of the particle.
 
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