Residue on steel after caustic cleaning

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Discussion Overview

The discussion revolves around the issue of removing a brown chalky residue from steel after cleaning aluminum with sodium hydroxide. Participants explore various chemical and mechanical methods for cleaning without damaging the steel, including the use of electrolytic methods and the effects of different cleaning agents.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant describes a brown chalky layer remaining on steel after using sodium hydroxide for cleaning aluminum and seeks a chemical removal method that does not affect the steel.
  • Another participant questions the term "affecting" and suggests the possibility of etching.
  • A participant mentions using sandpaper to remove scale residue but notes that it damages the steel and that alcohol and degreasers have been ineffective.
  • There is a suggestion that sodium aluminate should have dissolved in alcohol, indicating it may not be the residue in question.
  • One participant proposes sanding with fine grit sandpaper in the presence of a dilute sodium hydroxide solution to potentially dissolve some of the residue back into solution.
  • Another participant agrees that oxidation is likely the issue and expresses a preference for sanding over using additional chemicals.
  • A participant recommends using a concrete driveway cleaner or an electrolytic method for removing corrosion, noting that the electrolytic method can be adjusted for different types of rust and oxides.
  • One participant expresses interest in trying the electrolytic method when time permits and mentions having most materials needed for the process.

Areas of Agreement / Disagreement

Participants express differing opinions on the best method for removing the residue, with some favoring mechanical methods like sanding and others advocating for chemical or electrolytic approaches. No consensus is reached on a definitive solution.

Contextual Notes

Participants acknowledge the potential for damage to the steel when using mechanical methods and the uncertainty surrounding the chemical nature of the residue. There are also concerns about the safety and handling of chemicals involved in the cleaning process.

Mark Anderson
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After cleaning aluminum from steel I use with sodium hydroxide, there a brown chalky layer I want to clean off. Other than sanding, I cannot remove it. Is there a way to chemically remove it without affecting the steel?
 
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"Affecting?" Etching?
 
There's a scale residue left that I use sandpaper to remove.but sanding it also damages the steel. I've tried alcohol and degreasers with no luck.
 
Mark Anderson said:
There's a scale residue left that I use sandpaper to remove.but sanding it also damages the steel. I've tried alcohol and degreasers with no luck.
That won't work if it is what it could be.
Sodium aluminate should have dissolved in alcohol, so it can't be that.

You mean something like this perhaps.
http://www2.uni-siegen.de/~pci/versuche/english/v44-10.html

If so, aluminium oxide is fairly unreactive. In fact, it can be found on sandpaper since it is hard ( next to diamond I believe ).

You might try sanding with a very fine grit in the presence of sodium hydroxide solution, and see if some of the stuff will go back into solution.
Try a DILUTE solution, and a small section, since you don't want to be splashing the stuff around onto your clothes, skin and eyes.

I suppose previously, you just let the metal sit in an hydroxide solution to dissolve the Al.
Some of the Al went into the small microscopic indentations of the Fe during the original joining, and is now oxide.

Not 100% sure though if that is what you have there.
 
Yes I believe you are correct on the oxidization. As far as going over it again with the caustic solution, I think sanding it the normal way I do it is the best. I prefer not to deal with these chemicals more than necessary. Thank you for the input. This forum is very helpful and has much information.
 
This electrolytic method sounds like the ticket. When I get free time (tough with 3 kids), I will give it a test. I have all of the materials except for some rebar. I will let you guys know if it does.
 

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