I used to be involved in 'high power' model rocketry until a few years back when the hobby was blackballed by the ATF, the agency that tested and issued permits for handling the higher power stuff. This was due to concerns that some terrorist would use the hobby motors for nefarious purposes.
Anyhow... Most of the 'reloadable' solid fuel motors I had been familiar with at the time, used machined carbon for the nozzles due to its relatively low cost, high heat resistance and ease of machining. The single-use motors used some kind of impregnated black phenolic composite for their nozzles. The smallest motors (Estes) used fireclay, and to my knowledge, pyrotechnics people still use this type of nozzle on the rocket motors that lift their fireworks displays.
In my experience I don't remember anyone using ceramics. While the heat resistance of some ceramics may be attractive, most ceramics I'm aware of have poor resistance to mechanical loads. They tend to shatter which could be very dangerous.
Are you designing this motor for multiple uses? Is it solid-fueled, hybrid, or liquid?