Well Schwarzschild is fully spherically symmetric, so you instantly have the three rotational Killing Vectors: R=\partial_{\phi} =-y\partial_x+x\partial_y (this represents a rotation about z-axis), the other two are just rotations about x,y axis and are given as S=z\partial_x-x\partial_z and T=-z\partial_y+y\partial_z .
It is easy to see also by looking at the Schw metric in the usual Schw coords, that K=\partial_t is a KV, the metric components are time independent, it is a stationary (and static) spacetime, and we have time translational invariance.
So that is four KV. Maximally symmetric in 4 dimensions, means that the spacetime admits 1/2n(n+1)=10 KV, just like Minkowski, and as you say; for maximally symmetric spacetime we have constant curvature (say the Ricci scalar is the same everywhere in the spacetime).
Usually for Minkowski the other 6 KV represent spatial translational invariance in x,y,z, and boosts in x,y,z. One could translate these into the equivalent conditions in spherical polars I guess. But note, is Schwarzschild symmetric under translations in r? one could express the metric in the usual coords and see if ##\partial_r## satisfied Killing equation etc etc, but just by inspection do we really have radial symmetry? I would argue that things are clearly different at different radii. As you head out to r infty the spacetime looks Minkowskian, as you get closer to the centre of the BH the spacetime is more curved. Clearly we don't have radial symmetry so don't have a maximally symmetric spacetime.
Another way: what happens to the curvature invariants like R^{\rho...}R_{\rho...} ? At r=0 this blows up, and we know that we have a genuine singularity, at the horizon, this is finite (the apparent sing here was just a coordinate sing, and disappears in different coords etc)...thus curvature cannot be invariant, we don't have full translational invariance, and the spacetime is not maximally symmetric...
EDIT: actually I may be wrong about constant curvature here, after all Schw is a vacuum solution that means R_{\mu\nu}=0 suggesting the Ricci scalar is R=0 everywhere too, suggesting constant curvature, which is perhaps a distinct notion than the fact that certain curvature invariants like R^{\mu\rho\sigma\tau}R_{\mu\rho\sigma\tau} change. So maybe it is non-maximally symmetric but also constant curvature? hmm confused...
EDIT 2: If a spacetime was maximally symmetric it would obey R_{\rho \sigma \mu \nu}=\frac{R}{n(n-1)} \left(g_{\rho\mu}g_{\sigma\nu}-g_{\rho\nu}g_{\sigma\mu}\right) . In 2d finding that R is constant (i.e. zero in the case of Schw) would be sufficient to show a space max sym, since there is only one indepent component of the Riemann tensor, but in 4d there are 20, so knowing that the Ricci scalar is constant, does not prove constant curvature. We have a stronger condition than R=0 however, we have R_{\mu\nu}=0 everywhere (this is a 4x4 symmetric tensor, so has 10 indepenent components), thus we are left with 10 independent components of curvature. (Just the same number as the number of KV a Maximally symmetric space would have, but now we don't have ten KV so curvature is not constant).
What about the boost KV?