Simple (?) question regarding reflection of light

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SUMMARY

The discussion centers on the interaction of natural light with materials, specifically how light causes transitions of electrons between energy states, influencing the color perceived. It is established that while electronic transitions play a role in light absorption, large molecules also utilize vibrational, translational, and rotational states for this process. Reflection of light is clarified as a non-emissive phenomenon, where energy is not transferred to the reflecting medium. Fluorescence is highlighted as a specific case where absorbed energy is re-emitted as light.

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  • Familiarity with fluorescence and its mechanisms
  • Basic concepts of reflection and absorption of light
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rwooduk
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Does natural light when it hits an object cause transition of electrons between energy states and depending on the chemical composition of the material (hence the size of the transition) determine which colour we see?

So everything around us is emitting light (photons)? Everything around us is being excited by light and emitting its own intrinsic light?

I understand there is a reflection of certain wavelengths of light that depends on the absorption and reflective properties of the material, but I'm trying to understand this from a quantum point of view.

Thanks for any ideas.
 
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rwooduk said:
Does natural light when it hits an object cause transition of electrons between energy states and depending on the chemical composition of the material (hence the size of the transition) determine which colour we see?

Not always. Electronic transitions are only one means for large molecules (which is what most non-metallic materials are made of) to absorb light. There are other methods too, including different types of vibration states along with translational and rotational motion. These may or may not have quantized energy levels. If not, they can absorb a wide range of wavelengths instead of a single wavelength.

rwooduk said:
So everything around us is emitting light (photons)? Everything around us is being excited by light and emitting its own intrinsic light?

No, reflection is not a "emission" of light. The light is being reflected, so none of the energy of the reflected light is ever transferred to the reflecting medium. To emit light requires that the medium give off energy that it previously absorbed. A specific case of an object absorbing light and the re-emitting it is florescence, where specific electronic transitions in the material emit light after they have been excited.
 
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Drakkith said:
Not always. Electronic transitions are only one means for large molecules (which is what most non-metallic materials are made of) to absorb light. There are other methods too, including different types of vibration states along with translational and rotational motion. These may or may not have quantized energy levels. If not, they can absorb a wide range of wavelengths instead of a single wavelength.
No, reflection is not a "emission" of light. The light is being reflected, so none of the energy of the reflected light is ever transferred to the reflecting medium. To emit light requires that the medium give off energy that it previously absorbed. A specific case of an object absorbing light and the re-emitting it is florescence, where specific electronic transitions in the material emit light after they have been excited.

thats a very clear explanation, many thanks!
 

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