Yes, there are limits wrt theta and another wrt to phi.
This is be a double integral and not a single integral.
The limits are defined by the definition of spherical coordinates, although you do not need them to integrate your expression.
How would you integrate [itex]\int 5 d\phi[/itex]?
And how would you integrate [itex]\int 5 \sin(\theta) d\theta[/itex]?
Btw, in (these) spherical coordinates phi runs from 0 to 2pi, and theta runs from 0 to pi.