Solving for y-intercept on a wavefunction graph

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The discussion focuses on determining the normalization constant 'c' for a wavefunction graph, specifically using the integral of the squared wavefunction. The integral from -1 to 1 yields the equation 2/3 = 2c², leading to the conclusion that c = sqrt(1/3) = 0.58 nm-1/2. Participants clarify that the area under the squared wavefunction must be considered to compute probabilities, with the total area equating to 1. The probability of finding the particle between -1 and 1 nm is calculated as the integral of psi squared over that interval.

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40.EX16.jpg


What is c?




2. 1 = integral of wavefunction2 from -infinity to +infinity



3. From the graph, the area above the x-axis is 2/3 the total area. I solved the following integral (int) from -1 to +1:

2/3 = int(c2dx)

Obtaining 2/3 = 2c2

So c = sqrt(1/3) = 0.58 nm-1/2
 
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Linus Pauling said:
1.
40.EX16.jpg


What is c?

2. 1 = integral of wavefunction2 from -infinity to +infinity
3. From the graph, the area above the x-axis is 2/3 the total area. I solved the following integral (int) from -1 to +1:

2/3 = int(c2dx)Obtaining 2/3 = 2c2

So c = sqrt(1/3) = 0.58 nm-1/2

Remember, your are integrating the wave function squared, so you cannot just look at THAT graph. You must realize that the graph to look at is that graph with every value squared. What happens to negative values and fractions?
 
Last edited:
I'm lost. What equation describes the shape of the wavefunction given in the picture? I Understand that I will square that function, then integrate between the boundaries setting the integral equal to one, then solving for c...
 
Linus Pauling said:
I'm lost. What equation describes the shape of the wavefunction given in the picture? I Understand that I will square that function, then integrate between the boundaries setting the integral equal to one, then solving for c...

I'm not sure what function. I am just saying from the graph given, graph the square of the function (which you can just do visually by squaring all the \psi values). Then you can pull off the integration.
 
Also, you can just define the piecewise function. So -inf < x < -2 , psi = 0 and so on. Then just square each piece.
 
Ok, so the shape of the squared wavefunction is basically two smaller rectangles with height 0.25c^2 and base of length 1, and a bigger one with base of 2 and height c^2. Total area = the integral = 1 = (5/2)c^2, so c = 0.632

Correct?
 
I am also asked (and am confused about) computing the probability of finding thte particle between -1 and 1nm.

Do I simply take the integral/area of the "bigger rectangle" that goes from -1 to 1nm, whose are is 2c^2, then divide by the total area 2.5c^2, i.e. 80% probability?
 
Linus Pauling said:
Ok, so the shape of the squared wavefunction is basically two smaller rectangles with height 0.25c^2 and base of length 1, and a bigger one with base of 2 and height c^2. Total area = the integral = 1 = (5/2)c^2, so c = 0.632

Correct?

Yup.
 
Linus Pauling said:
I am also asked (and am confused about) computing the probability of finding thte particle between -1 and 1nm.

Do I simply take the integral/area of the "bigger rectangle" that goes from -1 to 1nm, whose are is 2c^2, then divide by the total area 2.5c^2, i.e. 80% probability?

Well now you know what c is and the probability of finding the particle between -1 and 1 is the integral of psi squared from -1 to 1.
 

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