Solving Thermo Problem: $\Delta U$, $\Delta K_{cm}$, $\Delta I$, $W_{ext}$, $Q$

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The discussion centers on the relationship between changes in internal energy (ΔU), kinetic energy (ΔK_cm), and potential energy (ΔI) as expressed by the equations ΔU = ΔK_cm + ΔI and ΔU = W_ext + Q, referencing the first law of thermodynamics. Participants explore whether work done (W_ext) and heat (Q) can be defined in terms of kinetic and potential energy. It is suggested that the first law of thermodynamics can be viewed as a restatement of the work-energy theorem. However, there is contention regarding the definitions of Q and W, particularly in scenarios like adiabatic processes in ideal gases, where heat transfer is zero but kinetic energy changes. The conversation highlights the complexities in reconciling thermodynamic principles with mechanical work and energy concepts.
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we know that $\Delta U$ $=$ $\Delta K_{cm}$ $+$ $\Delta I$
where $\Delta K_{cm}$ is the kinetic energy from cm frame of refrence and the other part is the change in change in potential energy due to various conservative forces.

also by first law of thermodynamics $\Delta U$ $=$ $W_{ext} + Q$
can we define $W_{ext}$ and $Q$ in terms of the other variables kinetic energy and potential energy
 
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pardesi said:
we know that

\Delta U =\Delta K_{cm} + \Delta I
where \Delta K_{cm} is the kinetic energy from cm frame of refrence and the other part is the change in change in potential energy due to various conservative forces.

also by first law of thermodynamics

\Delta U = W_{ext} + Q

can we define W_{ext} and Q in terms of the other variables kinetic energy and potential energy?

I changed all of your dollar signs to [ tex ] [ /tex ] tags (don't put the spaces) so that the LaTeX would work and the post would be readable. Now let me see if it can be understood...
 
work energy theorem

W_{ext} = \Delta KE + \Delta U

first law of thermo stated that way is just a restatement of this
 
ice109 said:
work energy theorem

W_{ext} = \Delta KE + \Delta U

first law of thermo stated that way is just a restatement of this
but how do you define W and Q using these
 
pardesi said:
but how do you define W and Q using these

you don't, it's the same formula, Q=ke and w=w
 
ice109 said:
you don't, it's the same formula, Q=ke and w=w
what is k,e,w
 
pardesi said:
what is k,e,w

it's simple
Q=KE and W_{ext}=W

your statement of the first law of thermo is the work-energy theorem.
 
ice109 said:
it's simple
Q=KE and W_{ext}=W

your statement of the first law of thermo is the work-energy theorem.
i don't think that's true because consider an ideal gas let it undergo adiabatic compression although the heat gained is 0 the temp. of body which is measured by change in kinetic energy changes
 
pardesi said:
i don't think that's true because consider an ideal gas let it undergo adiabatic compression although the heat gained is 0 the temp. of body which is measured by change in kinetic energy changes
I think the mistake I've made is the the U from the thermo equation equals KE from the work energy theorem and the Q from the thermo equation equals the U from the work energy theorem.

I would love to confirm or deny though.
 
  • #10
ice109 said:
I think the mistake I've made is the the U from the thermo equation equals KE from the work energy theorem and the Q from the thermo equation equals the U from the work energy theorem.

I would love to confirm or deny though.
actually the problem while doing that is we know as in the original U equation the change in kinetic energy as seen from c.m is work done by ext forces ,work done by internal conservative forces,work done by internal non conservative forces on the particles minus the work done by external forces on c.m but what
while change in internal energy is negative of work done by internal conservative forces .then while adding they cancel out then what's the use of defining them.

also now consider a gas in a cylinder the usual example with a pison.the pressure P of the gas be say less than P_{ext}then the net force on c.m due to these should be P_{ext}-P.P due to lower wall by Newtons third law,and P_{ext} due to external force above by piston
 
  • #11
someone please...
 
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