Speed of atoms ejected from an oven

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    Atoms oven Speed
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Discussion Overview

The discussion revolves around the average speed of atoms ejected from an oven at a given temperature T, particularly in the context of a Stern-Gerlach experiment. Participants explore the relationship between thermodynamic expressions for kinetic energy and the corresponding speed of atoms, comparing the root mean square (RMS) speed and the average speed derived from the Maxwell-Boltzmann distribution.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant proposes using the RMS speed derived from the expression E = 3/2 kT, leading to v = √(3kT/m), but questions its applicability in the context of a Stern-Gerlach experiment.
  • Another participant suggests that the average speed should be calculated using the Maxwell-Boltzmann distribution, resulting in ⟨v⟩ = √(8kT/πm), indicating a preference for this approach.
  • A participant expresses confusion about why their initial derivation, which uses kinetic energy, yields the RMS speed instead of the average speed, seeking clarification on the underlying reasoning.
  • Another participant notes that the RMS speed is appropriate for a gas where particles are equally likely to move in any direction, which leads to an average velocity of zero, questioning its relevance in the context of directional selection in a collimated beam.

Areas of Agreement / Disagreement

Participants do not reach a consensus on which speed expression is more appropriate for the Stern-Gerlach experiment. There are competing views regarding the relevance of RMS speed versus average speed, and the discussion remains unresolved.

Contextual Notes

Participants highlight the dependence on the definitions of speed and the conditions under which the average speed is calculated, particularly in relation to the directional selection of particles in a beam.

Jolb
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My question is this: what is the average speed of atoms released from an oven at some temperature T? For example, in a Stern-Gerlach experiment, hydrogen atoms are emitted from an oven and collimated into a beam by passing them through a slit (and then sent into an inhomogenous magnetic field, but I don't really care about these details for this particular question).

The reason I am confused about this is because my gut instinct would be to estimate this using the old thermodynamic expression for an ideal gas: E = 3/2 kT = 1/2 mv^2 which would imply v=\sqrt{\frac{3kT}{m}}
However, upon cracking open my thermodynamics textbook, it seems as though this is the RMS speed of atoms in a gas, rather than the boring-old average speed. The boring old average speed is found by calculating the expectation value of speed in the Maxwell-Boltzmann distribution, as such:
\langle v \rangle = \int_0^{\infty} v \, f(v) \, dv= \sqrt { \frac{8kT}{\pi m}}
They are very close: the factor of 3 just changes to 8/∏. But which one should I use in a Stern-Gerlach question? Which one would actually be observed in a collimated beam of atoms emitted from an oven at temperature T?

Edit: Just to clarify, even though I am using the symbol v, which is usually reserved for the velocity, here I am referring to the speed, which is equal to the magnitude of the velocity vector. That is to say, v=|v|.
 
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The second one.
 
The second one does seem more obvious, but why does my "gut instinct" derivation fail? It seems to me that if we know some expression for the average kinetic energy (E=3/2 kT), the expression should give the average speed, not the RMS speed. Why does that derivation give RMS rather than the correct answer?

Also, references would be appreciated.
 
Depends what you are deriving and how you go about it.

The rms velocity is what you get in the first one because the particles in the gas are equally likely to be heading an any direction - giving an average velocity of zero. You can see why this is not useful.

Put a hole in the walls though, and you are selecting for those particles that are headed in a subset of possible directions.
 

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