Stability of Highest Oxidation State

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SUMMARY

The stability of the highest oxidation state decreases from group 13 to group 17 due to the increasing difference in energy between ns and np orbitals as atomic number rises. This phenomenon is attributed to the increase in effective nuclear charge, which enhances the attraction of the nucleus for electrons. Consequently, the electron affinity becomes a crucial factor in understanding this trend. The relationship between these concepts is essential for grasping the underlying principles of oxidation states in the periodic table.

PREREQUISITES
  • Understanding of atomic structure and electron configurations
  • Familiarity with periodic trends in the periodic table
  • Knowledge of oxidation states and their significance in chemistry
  • Basic concepts of effective nuclear charge and electron affinity
NEXT STEPS
  • Research the concept of effective nuclear charge and its calculation
  • Study the trends in oxidation states across the periodic table
  • Explore the relationship between electron affinity and oxidation states
  • Learn about the differences in ns and np orbital energies in heavier elements
USEFUL FOR

Chemistry students, educators, and professionals interested in understanding periodic trends and oxidation states in elements from groups 13 to 17.

ritwik06
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Homework Statement



Why does the stability of highest oxiation state decreases from group 13 to group 17?

Ans: My book says, that with the increase in atomic number, difference in energies between ns and np orbitals increases. Is it right? If so then can u please explain what relation exists between the statements.
 
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It's better to consider this in terms of electron affinity. The energies between ns and np orbitals increases because of the increase in effective nuclear charge i.e. " it wants the electrons more " .
 

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