A subset U of V is a subspace of V if it satisfies the properties needed to be a vector space: additive identity; closure under vector addition; closure under scalar multiplication.
Check that your given subset satisfies the properties.
a) Is there an additive identity from your set for R^4?
b) If you take two vectors from your given space, a and b, is a+b still in your set?
c) Is the scalar multiple of any vector in your set still in the set?