Symmetry of the Bloch Ground State

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Discussion Overview

The discussion centers on the U(N) invariance of the Bloch ground state as mentioned in Hasan & Kane's review on topological insulators. Participants explore the implications of this invariance in the context of Hartree and Hartree Fock wavefunctions, as well as the relationship to Bloch functions and their transformation properties.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Jan questions the U(N) invariance of the Bloch ground state as stated in Hasan & Kane's review.
  • One participant explains that Hartree and Hartree Fock wavefunctions are invariant under unitary transformations of occupied and unoccupied orbitals, suggesting that Bloch functions have special properties related to this invariance.
  • A transformation to localized Wannier functions is mentioned as a popular unitary transformation related to Bloch functions.
  • Another participant corrects the earlier mention of "Brillouin functions" to "Wannier functions" and references Roy McWeeny's book for further details on the invariance of many-particle wavefunctions.
  • The invariance of determinants under unitary transformations is noted as a fundamental concept in this context.

Areas of Agreement / Disagreement

Participants express differing views on the clarity and implications of U(N) invariance in the context of Bloch ground states, indicating that the discussion remains unresolved regarding Jan's initial question.

Contextual Notes

There are references to specific transformations and concepts that may require further clarification, such as the distinction between Bloch and Wannier functions, and the foundational principles of linear algebra related to invariance.

Jan Paniev
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I was reading Hasan & Kane's review on topological insulators and right in the beginning, page 3, they say that the Bloch ground state is U(N) invariant. I do not see that. Would anyone be able to show it or point to a reference?

Thanks,
Jan.
 
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Any Hartree or Hartree Fock wavefunction is invariant with respect to a separate unitary U(N) and U(M) transformation of the N occupied and M unoccupied orbitals, respectively, among each other. The Blochfunctions are special insofar as they diagonalize the Hartree Fock effective single particle operators which have no fundamental significance, however.
A popular unitary transformation transforms the Bloch functions to the so called localized Brillouin functions (I hope, I remember the name correctly).
 
Thanks a lot for the answer. Would you know in which book I would be able to find the details?

Jan.
 
Sorry, the name is not Brillouin function but Wannier function.
They should be named in any book on solid state theory.
The invariance of many particle wavefunctions in quantum chemistry is discussed in depth in
Roy McWeeny, Methods of Molecular Quantum Mechanics, 1989.
Basically it is nothing more than the invariance of the determinant under unitary transformations as prooved in elementary linear algebra.
 

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