Terminology - the upper state

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Discussion Overview

The discussion revolves around the terminology used in a paper regarding radiative transfer, specifically focusing on the variable "N2," which is described as the number density of atoms in the upper state. Participants explore the meaning of "upper state" and its relation to atomic structure, particularly in the context of oxygen.

Discussion Character

  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant inquires whether "N2" refers to the number of atoms in the outer shell of oxygen, suggesting a count of 6.
  • Another participant clarifies that "upper state" refers to a higher-energy state and that N2 relates to the number of atoms in that excited state at a given time.
  • A later reply corrects a previous statement, indicating that the inquiry about outer shell electrons was a misunderstanding, emphasizing that the discussion pertains to atoms, not electrons.
  • It is noted that the "number density of atoms in the upper state" refers to an ensemble of atoms, with some in the lower state and some in the upper state.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the terminology and its implications, with some clarifications made but no consensus reached on the initial understanding of "N2" and its relation to atomic structure.

Contextual Notes

There are limitations in the initial definitions provided, and the discussion reflects a lack of clarity regarding the relationship between atomic structure and the concept of upper states in radiative transfer.

Paperfish
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Terminology - the "upper state"

Hi there!

I'm reading a paper at the moment that describes a formula for an absorption coefficient with regard to radiative transfer. One of the variables in it is referred to as "N2". It describes N2 as "The number density of atoms in the upper state".

With oxygen as an example, would N2 simply refer to the number of atoms in the outer shell? ie: 6?

My apologies if this is a bit obvious. I'm afraid I'm new to all this, and this terminology doesn't immediately appear to be standard.
 
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Paperfish said:
With oxygen as an example, would N2 simply refer to the number of atoms in the outer shell? ie: 6?
How many atoms are there in an atom?

Paperfish said:
formula for an absorption coefficient with regard to radiative transfer
So it is considering the transition between two states. The "upper state" then refers to the higher-energy state, and N2 is related to how many atoms are to found in that excited state at a given time.
 
My post finally gets a reply after 7 years, and it's revealed to not make sense. Amazing! Apologies, for that typo, it was meant to read:

"With oxygen as an example, would N2 simply refer to the number of electrons in the outer shell? ie: 6?"

And just to check, when you say "...and N2 is related to how many atoms are to found in that excited state at a given time", you do mean atoms and not electrons?
 
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Paperfish said:
My post finally gets a reply after 7 years,
We're doing some spring cleaning:
https://www.physicsforums.com/threads/pf-spring-cleaning.970133/
Paperfish said:
and it's revealed to not make sense. Amazing! Apologies, for that typo, it was meant to read:

"With oxygen as an example, would N2 simply refer to the number of electrons in the outer shell? ie: 6?"
No, this has nothing to do with electron shells.

Paperfish said:
And just to check, when you say "...and N2 is related to how many atoms are to found in that excited state at a given time", you do mean atoms and not electrons?
Yes, atoms. Not all the context was given, by I inferred that this deals with transitions between two states in an atom. The "number density of atoms in the upper state" refers to how many atoms are found in that upper (excited) state (it is not a single atom that is considered,but an ensemble of atoms, some will be in the lower state, some in the upper state).
 
Thank you so much for revisiting this and clarifying.
 
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