zapperzero said:
There's a bridge in Brooklyn you may be interested in. How much do you suppose this hydrogen would cost? Where would you get the carbon from? Where do you put the nuclear waste?
Actually hydrogen isn't attractive as transport fuel due to its low combustion heat per volume density.
Methanol being a one of so called “base chemicals” is widely produced now (~40 millions tons per annum) via the following reaction CO+2H2=>CH3OH http://www.topsoe.com/business_areas/methanol/~/media/PDF%20files/Methanol/Topsoe_large_scale_methanol_prod_paper.ashx
Process is very similar to Fischer-Tropsch process but uses another type of catalysts (e.g. Cu based instead of Fe or Co based).
Initial mix is made now via steam reforming natural gas (high temperature ~1000 deg Celsius):
CH4+H2O and may be O2 (if partial oxidation) => nCO+mH2+?Co2+?H2O (the quantity of last two depends on selectivity of catalyst)
If we need not methanol but need pure hydrogen for example for hydrocracking process or fertilizer (ammonia) manufacturing the second step of lower temperature process is carried out:
CO+H2O=>H2+CO2
And the second process produces very large quantity of carbon dioxide.
This is the most common for today’s level of technology and today’s parity of prices on electricity and hydrocarbons.
Today's annual production of ammonia exceeds 120 million tons
http://www.greener-industry.org.uk/pages/ammonia/1ammoniaapq.htm
And so, if even not considering hydrocracking process also consuming a big quantity of hydrogen, annual production of hydrogen is not less than 3/17*120=21 million tons.
Thinking strategically, crude oil and gas will end in 30-50 years.
In process of an exhaustion of stocks prices inevitably will grow having exceeded the certain threshold when it becomes more favourable to make hydrogen via water electrolyze. And power source here – only nuclear fission or nuclear fusion.
Carbon source in this case will be only the coal gasification in which target reaction is: 2C+O2=>2CO
Manufacturing of liquid hydrocarbons fromcoal is a so called Coal-to-Liquid (CTL) process.
In this process we can produce hydrogen without usage of electricity as well via mentioned above “low temperature” process. But carbon dioxide pollution in this case will be much higher than in case we would use natural gas as carbon source (Gas-to-Liquid).
Note#1: Fischer-Tropsch process has been developed since 1925 in Germany and was used by Nazi for producing of motor fuel from coal in WW2 when they have only not large oil deposits in Romania. Production scale exceeded 5million metric tons per year.
Note#2: One of leaders in CTL process is a South African company SASOL who developed that when South Africa was being embargoed by UN by the reason of apartheid.
PS#1: Nuclear wastes are significant challenge. So, let's develop fusion producing no or much less wastes.
PS#2: I have a book written in late 40s in which is described in details how German chemicists prepared FT and other catalysts and how they build reactors. Now such information as a rule is an industrial secret (know-how) of such companies such as SASOL, Akzo Nobel, etc.