mheslep said:
Thanks for this.
It seems to me the problem would not be the waste of thorium, but the loss of a neutron on Pa-233, and another on the subsequent U-234, both with good capture cross section. With all that you still calculated a sufficient breeding ratio? Or is the answer to keep adding other fissile material until it does? If so then the design adds back the long lived actinides to the waste stream, the lack of which was one advantage of the thorium reactor.
About 11% of neutrons captured by U233 produce U234 rather than fission, with a small amount of U234 coming from Pa234 decay. U234 is parasitic, but it's absorption by neutrons produces U-235, which is fissionable, although some forms U236, which leads to Np236, or n-capture to U237, which leads to Np237, but at much smaller levels than in LWR fuel containing U235 fissile material. Without U238, the transuranics are relatively low.
Breeder cores are designed with reflectors, since any core will 'leak' neutrons. So the reflector are used to reflect neutrons back to the active core, and use the neutrons that don't leak for converting fertile material to fissile material. The other benefit is to reduce neutron fluence to the containment/pressure vessel that holds the core.
Fuel Summary Report: Shippingport Light Water Breeder Reactor
http://www.inl.gov/technicalpublications/Documents/2664750.pdf
A summary of the Shippingport experience with thoria-based fuel. I communicated with the author for one project I did about 25 years ago.
http://large.stanford.edu/courses/2009/ph204/coleman1/docs/10191380.pdfArticle in American Scientist - needs subscription or purchase.
http://www.americanscientist.org/my_amsci/restricted.aspx?act=pdf&id=36745203226947
The image shows 'green' pellets, i.e, the thoria-urania powder combined with binder and die lubricant has been pressed, usually to about 50-60% of theoretical density (TD) of the stoichiometric ceramic, and awaiting sintering, in a furnace at about 1700-1800 C. It will probably achieve ~95 to 96% of TD.
Criticism - http://www.americanscientist.org/issues/pub/2010/6/not-so-fast-with-thorium
The criticism of the HTGR has nothing to do with thorium. It has to do with the fuel and reactor technology at the time, and the same would have happened with U-based fuel. Similarly, Shippingport was the first large LWR system to be devoted to commercial electricity. It was scheduled for shutdown, and researchers took advantage of it to load the core with thorium-based fuel as a demonstration. There were issues with the thorium fuel cycle at the time, mainly the breeding and reprocessing part, and some of those difficulties made it less attractive than the uranium-based fuel cycle. Of course, there were strong economic interests concerning the use of uranium.
We have learned a lot since then.