The role of surface tension in capillarity

AI Thread Summary
Surface tension plays a crucial role in capillarity by exerting an upward force on water in a tube until it balances with gravity. This upward force is attributed to both surface tension and adhesive forces between the water and the container material. The meniscus behavior varies depending on the liquid; for water in glass, it rises due to adhesion, while for mercury, it descends. The discussion highlights a debate over whether surface tension or adhesive forces are more responsible for the observed capillary action. Ultimately, both perspectives contribute to understanding the mechanics of fluid movement in narrow spaces.
Shackleford
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From what I've read, the surface tension pulls upward on the given volume of water and when this surface tension force equals the force of gravity (weight), there is no more vertical movement up the tube.

Why is it said that the surface tension pulls upward on the mass of water when surface tension refers to the increased horizontal intermolecular attraction of the top surface layer? Why do you not say that the upward force on the volume of water is the adhesive forces from the container material?
 
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Hi Shackleford! :smile:

I think both views are correct …

a) Surface tension is a force parallel to the liquid surface and pointing towards the solid surface.

So when the meniscus goes up (as with water in a glass tube), the force is up, but when it goes down (as with mercury in a glass tube), the force is down.

In other words …
Shackleford said:
… the surface tension pulls upward on the given volume of water and when this surface tension force equals the force of gravity (weight), there is no more vertical movement up the tube.
b) But the reason why the meniscus is up for water on glass is that water adheres to glass

and so …
Shackleford said:
the upward force on the volume of water is the adhesive forces from the container material.

(And see also http://en.wikipedia.org/wiki/Surface_tension#Liquid_in_a_vertical_tube" for a third argument about minimising the surface area of the water. :wink:)
 
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Shackleford said:
From what I've read, the surface tension pulls upward on the given volume of water and when this surface tension force equals the force of gravity (weight), there is no more vertical movement up the tube.

Why is it said that the surface tension pulls upward on the mass of water when surface tension refers to the increased horizontal intermolecular attraction of the top surface layer? Why do you not say that the upward force on the volume of water is the adhesive forces from the container material?

I understand the molecular interpretation of surface tension is commonly taught that way, but I'm not convinced it provides any real insight. It's much simpler to see the result in terms of continnum mechanics:

http://www.agron.iastate.edu/soilphysics/a577cap.html
 
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