Engineering Thermal expansion coefficient calculation — where is my mistake?

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SUMMARY

The discussion focuses on the calculation of the thermal expansion coefficient using the Van der Waals (VDW) state equation. A key issue identified is the incorrect use of units for specific volume; it must be expressed in m3/mol instead of m3/kg. This adjustment ensures that the units in the denominator of the thermal expansion coefficient equation are consistent, specifically resulting in Joule/mol. The correction leads to logical and valid results for the thermal expansion coefficient.

PREREQUISITES
  • Understanding of the Van der Waals state equation
  • Familiarity with thermal expansion coefficient calculations
  • Knowledge of unit conversions, specifically between m3/kg and m3/mol
  • Basic principles of thermodynamics and energy units
NEXT STEPS
  • Review the Van der Waals equation for real gas behavior
  • Study unit conversion techniques in thermodynamic calculations
  • Explore the implications of thermal expansion in different materials
  • Learn about other equations of state and their applications
USEFUL FOR

This discussion is beneficial for students and professionals in thermodynamics, chemical engineering, and materials science, particularly those involved in calculations related to thermal properties of substances.

ReuvenD10
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Homework Statement
Get values of thermal expansion coefficient
Relevant Equations
below
Hello everyone,
Once I got through the VDW state equation I came to the expression of the thermal expansion coefficient. When I place the values I get an illogical answer. Is there a problem with the units? (Please ignore the values)

Thanks.

1611562286615.png


This is the unit equation I get to and get stuck:
1611562244596.png
 

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You need to use a value of v in m3/mol.
 
ReuvenD10 said:
Homework Statement:: Get values of thermal expansion coefficient
Relevant Equations:: below

Hello everyone,
Once I got through the VDW state equation I came to the expression of the thermal expansion coefficient. When I place the values I get an illogical answer. Is there a problem with the units? (Please ignore the values)

Thanks.

View attachment 276808

This is the unit equation I get to and get stuck:
View attachment 276807
That specific volume (##m^3/Kg##) would be compatible to be used in the members of summation of the denominator of that equation only if multiplied by the molar mass of the specific substance (##Kg/mol##); therefore, the units of v should be expressed in ##m^3/mol##, rather than ##m^3/Kg##.
The units of each member of summation of the denominator would then be Joule/mol.
 
thanks. it work.
 

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