That is a really general question.
RF is just a sinewave with a high frequency. At the transmitting end, it is usually measurable in volts rather than microvolts. RF may or may not have information on it. There are various ways of doing this, but Amplitude modulation and Frequency modulation (AM and FM) are common examples.
Amplifiers for RF usually use tuned circuits as loads rather than resistors.
Not sure what you mean by coupling network. This term just means to connect something to something else, often with a tuned circuit, although transformers using ferrite cores are also used.
These networks are used to isolate circuits from each other while allowing RF to pass between them and also to achieve impedance matching.
You apparently already have a book about this, so maybe you could read on and if you don't understand something specific, then ask.
RF usually starts with an oscillator which is arranged to be as stable as possible.
This oscillator will not normally be on the final output frequency of the transmitter. Mixers are used to get the oscillator output to the final frequency and amplified enough to give the desired power output.
I always suggest that someone try to get into a hobby level class. It may cost a few dollars, but you need to get the fundamentals sorted out in a logical process.
Try to find a Radio Amateur club in your area or check with a local Technical College.