Van der Waals' Forces and Hydrogen Bonding

Join the discussion
Registration is free. Ask a follow-up in this thread, or start your own.
2 replies · 2K views
Priyadarshini
Messages
191
Reaction score
4
Induced dipoles result in Van der Waals' forces and permanent dipoles in hydrogen bonds, right? But how do you know is a compound has formed hydrogen bonds or Van der Waals' forces? For example, HF forms hydrogen bonds while HCl forms Van der Waals' forces and not hydrogen bonds. But in HCl, H is delta positive and Cl is delta negative, so shouldn't it form hydrogen bonds? But then when do Van der Waals' forces form?
Thanks.
 
Chemistry news on Phys.org
Those categories don't have a sharp dividing line. Some bonds are very van-der-Waals-like, some are very hydrogen-bond-like, some are somewhere in between.
 
mfb said:
Those categories don't have a sharp dividing line. Some bonds are very van-der-Waals-like, some are very hydrogen-bond-like, some are somewhere in between.
Oh, thanks!