Vapor density in kg/m3 in CO2 absorber

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    Co2 Density Vapor
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Discussion Overview

The discussion revolves around calculating the vapor density of a gas mixture exiting a Steam Methane Reformer, specifically under conditions of temperature, pressure, and flow rate. The focus is on determining the appropriate formula or method for this calculation, considering the mixture's composition and properties.

Discussion Character

  • Technical explanation
  • Mathematical reasoning

Main Points Raised

  • Tim seeks assistance in calculating vapor density using given temperature, pressure, flow rate, and molecular weight of a gas mixture primarily composed of hydrogen.
  • Tim provides additional context about the gas composition after water gas shifts, detailing the mol% of each component in the mixture.
  • One participant suggests calculating total density from the partial pressures of each gas constituent, noting that total pressure equals the sum of the partial pressures.
  • Tim mentions using the Ideal Gas Law, assuming the gas behaves ideally with a compressibility factor of 1.

Areas of Agreement / Disagreement

Participants have not reached a consensus on the best method for calculating vapor density, and multiple approaches are being discussed without resolution.

Contextual Notes

Assumptions about ideal gas behavior and the equal temperature of the gas mixture are noted, but the implications of these assumptions remain unresolved.

timvk
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hello all,

I got a bit of a problem. I want to calculate the vapor density (kg/ m3 or lbs/ ft3) with the following facts:

temp: 40C
pressure : 20-31 bar
flow rate: 1000-10000 kmole/ hr
MW avg: 10-12 g/ mol (it is a mixture of H2, CO, CO2, CH4, H2O)> mostly H2


I wanted to know which formula/ method I have to use to calculate the vapor density. Hope someone can help me

Cheers,

Tim
 
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maybe it makes it more realistic when I say this:

It is about a exit gas from a Steam Methane Reformer after water gas shifts.

The mol% of the exact compositions are:
75.22% H2
19.27% CO2
4.22% CH4
0.30% CO
0.98% N2
rest is water

temp is 40C
pressure: 26.5 bar
4640 kmole/ hr

Still hope someone could help with this problem
 
Hi Tim,
You should be able to calculate total density from the partial pressures. Total pressure is equal to the sum of the partial pressures of each constituent. Assume also the temperature of all the gasses in the mix are equal.

See if this helps at all: http://www.mikeblaber.org/oldwine/chm1045/notes/Gases/Mixtures/Gases06.htm
 
Thanks,

I will look it up in more detail. For now I used the Ideal gas law (assumed it is an ideal gas with compressibility of 1)

cheers,
 

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