Vapor pressure of water (kinetics)

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SUMMARY

The discussion centers on the collection of hydrogen gas (H2) generated from the reaction between a metal and hydrochloric acid, and the challenge of separating water vapor from the collected gas. Participants confirm that the equilibrium vapor pressure of water at room temperature can be used to estimate the contribution of water vapor to the total gas volume. It is established that allowing the reaction to continue for a longer duration can help achieve equilibrium between liquid water and water vapor, thus providing a clearer measurement of the hydrogen gas collected.

PREREQUISITES
  • Understanding of gas collection methods in chemistry
  • Knowledge of equilibrium vapor pressure concepts
  • Familiarity with the properties of hydrogen gas and water vapor
  • Experience with desiccants and their applications in gas purification
NEXT STEPS
  • Research the use of desiccants for gas drying techniques
  • Study the principles of vapor-liquid equilibrium in thermodynamics
  • Learn how to calculate the equilibrium vapor pressure of water at various temperatures
  • Explore methods for accurately measuring gas volumes in chemical reactions
USEFUL FOR

Chemistry students, laboratory technicians, and researchers involved in gas collection and analysis, particularly those working with hydrogen and water vapor interactions.

feiyangflash
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Hi All,

I tried to collected hydrogen gas generated from the reaction between a metal and hydrochloric acid. I put a inverted conical flask in the water, and the generated H2 would push the water out of the flask, and then the H2 was collected. However, I guess there is water vapor mixed together with the H2, and therefore the gas volume I read is actually for the summation of H2 and water vapor, rather than the H2. I could find the equilibrium vapor pressure of water at room temperature. However, I don't know whether the equilibrium between liquid water and water vapor is reached or not. The whole reaction last for 1/2 hour.

Is there a way to figure out how much the pressure contributed by water vapor is?

Thank you!

Fei
 
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could you simply use a desiccant to get rid of the water vapor?

if, as you suggest, that there may be a non-equilibrium amount of water vapor in your system, it would be difficult to attach a numerical value to how much is present.
 
Thank you for the reply!

I keep it for much longer time, so the equilibrium between the water vapor and liquid water is reached, and then I know how much water vapor there is in the mixed gas of hydrogen and water vapor.


uby said:
could you simply use a desiccant to get rid of the water vapor?

if, as you suggest, that there may be a non-equilibrium amount of water vapor in your system, it would be difficult to attach a numerical value to how much is present.
 

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