Wavefunction obeying Schrodinger equation.

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hhhmortal
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Homework Statement



I've attached my past paper question, which contains the relevant integral identity too.


The Attempt at a Solution



This question is relatively simple, yet I can't seem to complete it.

I used the Schrödinger equation which is:

-(ħ²/2m)[tex]\nabla^2[/tex]u + Vu = Eu

I then used the identity given in the question, to differentiate the wavefunction w.r.t to r twice. (In this part I had to differentiate by products since there was another factor of r).

Differentiating the wavefunction twice gave me:

(Z²/a²).r.u

When I put this into the Schrödinger equation above, knowing V and E, I don't get the correct answer.
 
Last edited:
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I forgot to say, that it's the first part of the question which I'm having trouble with.Thanks.
 

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  • QM question s.jpg
    QM question s.jpg
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Can't tell you where you go wrong since you barely show any work, but I can tell you two things.

1) Your Schrödinger equation is incorrect.

2) You differentiated the wave function twice incorrectly.
 
I've fixed that now. I differentiated the wavefunction using the product rule:

using the identity given in the question, I had:

d²/dr²[ r. exp(-Zr/a)] Is this what I need to differentiate?
 
Out of interest, how would one go about solving the third part of this question?