What are the attractive forces in a neutral fluid?

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Discussion Overview

The discussion revolves around the nature of attractive forces in neutral fluids, specifically focusing on water and its behavior when heated. Participants explore the concept of intermolecular forces and their role in temperature changes across different states of matter.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant questions the existence of attractive forces between neutral molecules, specifically in the context of water, when heat is applied.
  • Another participant suggests looking up "van der Waals forces" as a potential explanation for intermolecular attractions.
  • A further contribution mentions that van der Waals forces consider both the physical size of gas particles and intermolecular attractions but does not clarify the mechanisms behind these attractions.
  • One participant expresses interest in the states of matter and notes that van der Waals primarily addresses the gas state.
  • Another participant points out that water is a polar molecule, which, while neutral overall, has a dipole electric field due to uneven electron sharing, suggesting that intermolecular forces may arise from electric forces.

Areas of Agreement / Disagreement

Participants express differing views on the existence and nature of attractive forces between neutral molecules, with some proposing that intermolecular forces exist while others remain uncertain about their mechanisms.

Contextual Notes

The discussion highlights a lack of consensus on the definitions and explanations of intermolecular forces, particularly in relation to neutral molecules and various states of matter.

rogerk8
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Hi!

I wonder about how for instance water temperature is changed with regard to applied heat.

You all know that if you take ice and heat it up temperture will climb until it reaches 0C.

When it reaches 0C it however stobs climbing in tempertaure regardless of how much heat you supply.

It is said that heat is needed to overcome the attractive forces of the molecules instead of just giving them higher speed (i.e Ek and thus temperature).

It is said that these attractive forces constitute a potential energy to be overcome before the molecules can move faster thus giving the fluid higher temperature, Ek.

I just wonder what these attractive forces are because as far I understand there is no attractive forces between neutral molecules.

And regardless of state (solid, liquid or vapour) neutral H20 is still the molecule in mind.

So where is the attractive forces?

Roger
 
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rogerk8 said:
as far I understand there is no attractive forces between neutral molecules.

Look up "van der Waals forces".
 
Van der Waal considers both the physical size of gas particles and "intermolecular attractions".

I have read this fantastic site: http://www.et.byu.edu/~rowley/ChEn273/Topics/Mass_Balances/Single_Phase_Systems/Van_der_Waals_Equation_of_State.htm

And it states that there are "intermolecular attractions".

But it never explains how or why.

So my question remains, how can there be intermolecular attractions between neutral molecules?

Roger
 
Another thing, I am interested in all the states of matter.

Van der Waal only considers the gas state.

Roger
 
I can't answer in general, but at least water is a polar molecule. Taken as a whole it is neutral, but it isn't made of neutral particles. Since the particles are separated, it has a dipole electric field. I forget a kot of chem, but I bet a lot of intermolecular forces are electric forces due to uneven electon sharing.
 
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