What are the attractive forces in a neutral fluid?

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SUMMARY

The discussion centers on the attractive forces present in neutral fluids, specifically water, and how these forces affect temperature changes when heat is applied. It is established that while water is a neutral molecule, it exhibits polar characteristics, leading to intermolecular attractions, primarily due to dipole interactions. The concept of van der Waals forces is introduced as a key factor in understanding these attractions, which are essential for overcoming potential energy barriers during phase transitions. The conversation highlights the need for clarity on how these forces operate in various states of matter.

PREREQUISITES
  • Understanding of molecular polarity and dipole interactions
  • Familiarity with van der Waals forces and their implications
  • Basic knowledge of phase transitions in matter
  • Concept of potential energy in molecular systems
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  • Research the role of van der Waals forces in different states of matter
  • Explore the properties of polar molecules and their intermolecular interactions
  • Study the principles of thermodynamics related to phase changes
  • Investigate the effects of temperature on molecular motion and energy
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Students and professionals in chemistry, physicists studying thermodynamics, and anyone interested in the molecular behavior of fluids and phase transitions.

rogerk8
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Hi!

I wonder about how for instance water temperature is changed with regard to applied heat.

You all know that if you take ice and heat it up temperture will climb until it reaches 0C.

When it reaches 0C it however stobs climbing in tempertaure regardless of how much heat you supply.

It is said that heat is needed to overcome the attractive forces of the molecules instead of just giving them higher speed (i.e Ek and thus temperature).

It is said that these attractive forces constitute a potential energy to be overcome before the molecules can move faster thus giving the fluid higher temperature, Ek.

I just wonder what these attractive forces are because as far I understand there is no attractive forces between neutral molecules.

And regardless of state (solid, liquid or vapour) neutral H20 is still the molecule in mind.

So where is the attractive forces?

Roger
 
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rogerk8 said:
as far I understand there is no attractive forces between neutral molecules.

Look up "van der Waals forces".
 
Van der Waal considers both the physical size of gas particles and "intermolecular attractions".

I have read this fantastic site: http://www.et.byu.edu/~rowley/ChEn273/Topics/Mass_Balances/Single_Phase_Systems/Van_der_Waals_Equation_of_State.htm

And it states that there are "intermolecular attractions".

But it never explains how or why.

So my question remains, how can there be intermolecular attractions between neutral molecules?

Roger
 
Another thing, I am interested in all the states of matter.

Van der Waal only considers the gas state.

Roger
 
I can't answer in general, but at least water is a polar molecule. Taken as a whole it is neutral, but it isn't made of neutral particles. Since the particles are separated, it has a dipole electric field. I forget a kot of chem, but I bet a lot of intermolecular forces are electric forces due to uneven electon sharing.
 
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